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701122

Sigma-Aldrich

氯化铁(III)

greener alternative

sublimed grade, ≥99.9% trace metals basis

别名:

三氯化铁, 氯化铁, 铁盐

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About This Item

线性分子式:
FeCl3
CAS号:
7705-08-0
分子量:
162.20
EC號碼:
231-729-4
MDL號碼:
MFCD00011005
分類程式碼代碼:
12352302
PubChem物質ID:
329762262
NACRES:
NA.23

等級

sublimed grade

蒸汽密度

5.61 (vs air)

蒸汽壓力

1 mmHg ( 194 °C)

化驗

≥99.9% trace metals basis

形狀

powder or crystals

反應適用性

reagent type: catalyst
core: iron

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

技術

cell culture | mammalian: suitable

雜質

≤1000.0 ppm Trace Metal Analysis

mp

304 °C (lit.)

應用

battery manufacturing

環保替代類別

Aligned,

SMILES 字串

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI 密鑰

RBTARNINKXHZNM-UHFFFAOYSA-K

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Iron(III) chloride is brownish to black crystalline solid that is highly soluble in water. As a moderately strong Lewis acid, FeCl3 can form complex compounds and adducts with Lewis bases, making it a useful catalyst in various chemical reactions.

應用

在氢作用下与其他金属卤化物气相共还原生成细分的金属互化物，它们可用作具有有效的热电性、磁性和抗氧化性的结构材料或化合物。
Iron(III) chloride can be used:
  • As a precursor to prepare Fe(III)-chlorophyll complex. Fe(III) enhances the performance of chlorophyll as a dye sensitizer in DSSCs by forming complex compounds with metal-ligand charge transfer properties, leading to increased efficiency and improved paramagnetic properties.
  • As a catalyst /modifying agent to prepare high performance porous carbon for lithium-ion battery anodes. The addition of FeCl3 enhances the graphitization of porous carbon without significantly affecting the layer spacing and also the specific surface area and pore volume of porous carbon.
  • As a co-catalyst to fabricate liquid catalyzed fuel cell (LCFC) for direct conversion from carbohydrates to electricity. It helps to improve the hydrolysis of carbohydrate and enhances the electron transfer from carbohydrates to anode.

象形圖

CorrosionExclamation mark
GHS05,GHS07

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 1

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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分析证书(COA)

Lot/Batch Number
MKCC8725
MKCB9069
MKCB8991
MKCB3622
MKBZ4373V

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氯化铁(III) 六水合物 ACS reagent, 97%

Sigma-Aldrich

236489

氯化铁(III) 六水合物

氯化亚铁 四水合物 99.99% trace metals basis

Sigma-Aldrich

380024

氯化亚铁 四水合物

Optimum reaction conditions for the polymerization of pyrrole by iron (III) chloride in aqueous solution.
Armes SP.
Synthetic Metals, 20(3), 365-371 (1987)
Recent uses of iron (III) chloride in organic synthesis.
Diaz DD, et al.
Current Organic Chemistry, 10(4), 457-476 (2006)
Kailiang Wang et al.
The Journal of organic chemistry, 74(2), 935-938 (2008-12-05)
Easily available and nontoxic FeCl(3) catalyzes intramolecular oxidative coupling for the direct construction of the phenanthrene ring using meta-chloroperbenzoic acid as sole oxidant at room temperature in excellent yields. The mechanistic investigations show that FeCl(3)-catalyzed coupling proceeds through the heterolytic
Photoredox chemistry of iron (III) chloride and iron (III) perchlorate in aqueous media. A comparative study.
David F and David PG.
The Journal of Physical Chemistry, 80(6), 579-583 (1976)
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
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