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701122

Sigma-Aldrich

氯化铁(III)

greener alternative

sublimed grade, ≥99.9% trace metals basis

别名:

三氯化铁, 氯化铁, 铁盐

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About This Item

线性分子式:
FeCl3
CAS号:
7705-08-0
分子量:
162.20
EC號碼:
231-729-4
MDL號碼:
MFCD00011005
分類程式碼代碼:
12352302
PubChem物質ID:
329762262
NACRES:
NA.23

等級

sublimed grade

品質等級

100

蒸汽密度

5.61 (vs air)

蒸汽壓力

1 mmHg ( 194 °C)

化驗

≥99.9% trace metals basis

形狀

powder or crystals

反應適用性

reagent type: catalyst
core: iron

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

技術

cell culture | mammalian: suitable

雜質

≤1000.0 ppm Trace Metal Analysis

mp

304 °C (lit.)

應用

battery manufacturing

環保替代類別

Aligned,

SMILES 字串

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI 密鑰

RBTARNINKXHZNM-UHFFFAOYSA-K

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應用

三氯化铁可通过聚合反应合成聚吡咯。该化合物可作为分子内氧化偶联反应的催化剂，用于制备菲环。它是一种廉价、环保的氧化剂，可用于以下有机反应：
  • 聚合
  • 氧化
  • 氧化偶联
  • 减量
  • C-C 键形成
  • Ferrier 重排
  • 多组分冷凝
  • Friedel-Crafts 反应
  • 环化作用
  • 苷化
  • Prins 型环化
在氢作用下与其他金属卤化物气相共还原生成细分的金属互化物，它们可用作具有有效的热电性、磁性和抗氧化性的结构材料或化合物。

象形圖

CorrosionExclamation mark
GHS05,GHS07

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

儲存類別代碼

8B - Non-combustible, corrosive hazardous materials

水污染物質分類（WGK）

WGK 1

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

分析证书(COA)

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氯化铁(III) 六水合物 ACS reagent, 97%

Sigma-Aldrich

236489

氯化铁(III) 六水合物

氯化亚铁 四水合物 99.99% trace metals basis

Sigma-Aldrich

380024

氯化亚铁 四水合物

Optimum reaction conditions for the polymerization of pyrrole by iron (III) chloride in aqueous solution.
Armes SP.
Synthetic Metals, 20(3), 365-371 (1987)
Recent uses of iron (III) chloride in organic synthesis.
Diaz DD, et al.
Current Organic Chemistry, 10(4), 457-476 (2006)
Kailiang Wang et al.
The Journal of organic chemistry, 74(2), 935-938 (2008-12-05)
Easily available and nontoxic FeCl(3) catalyzes intramolecular oxidative coupling for the direct construction of the phenanthrene ring using meta-chloroperbenzoic acid as sole oxidant at room temperature in excellent yields. The mechanistic investigations show that FeCl(3)-catalyzed coupling proceeds through the heterolytic
Photoredox chemistry of iron (III) chloride and iron (III) perchlorate in aqueous media. A comparative study.
David F and David PG.
The Journal of Physical Chemistry, 80(6), 579-583 (1976)
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
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