O0376

草酸 二水合物

ReagentPlus^®, ≥99.0% (GC)

• 别名: 乙二酸
• 线性分子式: HO₂CCO₂H · 2H₂O
• CAS号: 6153-56-6
• 分子量: 126.07
• Beilstein: 3679436
• EC號碼: 205-634-3
• MDL號碼: MFCD00149102
• 分類程式碼代碼: 12352100
• eCl@ss: 39021701
• PubChem物質ID: 57654475
• NACRES: NA.21

属性

• 等級: reagent
• 品質等級: 200
• 蒸汽密度: 4.4 (vs air)
• 蒸汽壓力: <0.01 mmHg ( 20 °C)
• 產品線: ReagentPlus^®
• 化驗: ≥99.0% (GC)
• mp: 104-106 °C (lit.)
• 官能基: carboxylic acid
• SMILES 字串: [H]O[H].[H]O[H].OC(=O)C(O)=O
• InChI: 1S/C2H2O4.2H2O/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H2
• InChI 密鑰: GEVPUGOOGXGPIO-UHFFFAOYSA-N

说明

一般說明

Oxalic acid dihydrate (OAD) crystals are reported to be monoclinic with P2₁/n space group. The electron density of OAD has been obtained using X-ray diffraction studies under high resolution.

應用

Oxalic acid dihydrate may be used:

• As a catalyst in the preparation of tetrahydroquinoline derivatives via imino Diels-Alder reaction.
• As a homogeneous catalyst in the preparation of highly functionalized piperidines via multi-component reaction.
• As an oxidant for the formation of triazolinediones from corresponding urazoles and bisurazoles via oxidation.
• In the transformation of thiols to nitrosothiols by reacting with sodium nitrite.

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

安全信息

• 象形圖: GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H302 + H312,H318
• 防範說明: P264 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P362 + P364
• 危險分類: Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 1
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves