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Merck

937037

Sigma-Aldrich

cataCXium Pd G4

new

别名:

cataCXium Pd G4, [di(adamantan-1-yl)(butyl)phosphine](methanesulfonato-κO)[2′-(methylamino)-2-biphenylyl]palladium

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About This Item

经验公式(希尔记法):
C38H54NO3PPdS
分子量:
742.30
分類程式碼代碼:
12352100

形狀

solid

品質等級

成份

, 4-6 wt. % (loading of catalyst)

反應適用性

reagent type: catalyst
core: palladium
reaction type: Cross Couplings

SMILES 字串

CCCCP([C@@]12C[C@H]3C[C@@H](C1)C[C@@H](C2)C3)[C@@]4(C5)C[C@H]6C[C@H](C[C@@H]5C6)C4.CNC7=C(C8=CC=CC=C8[Pd]OS(C)(=O)=O)C=CC=C7

InChI

1S/C24H39P.C13H12N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h17-22H,2-16H2,1H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1

InChI 密鑰

ROZFJYIWIVSDBR-UHFFFAOYSA-M

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相关类别

一般說明

A fourth generation (G4) Buchwald precatalyst on glass beads that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.

應用

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For general uses, product is also available in powdered form (900349)

特點和優勢

For feature and benefits, please visit the technical article on Buchwald G4 Precatalysts. https://www.sigmaaldrich.com/US/en/technical-documents/technical-article/chemistry-and-synthesis/cross-coupling/g3-and-g4-buchwald-precatalysts

相關產品

产品编号
说明
价格

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析证书(COA)

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