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蒸汽密度
4.89 (vs air)
品質等級
蒸汽壓力
24.09 psi ( 55 °C)
7.89 psi ( 20 °C)
等級
purum
化驗
≥99.0% (GC)
包含
silver wool as stabilizer
雜質
≤0.5% CH2I2
折射率
n20/D 1.530
n20/D 1.531 (lit.)
bp
41-43 °C (lit.)
41-43 °C
mp
−64 (lit.)
溶解度
water: soluble 14 g/L at 20 °C
密度
2.28 g/mL at 25 °C (lit.)
SMILES 字串
CI
InChI
1S/CH3I/c1-2/h1H3
InChI 密鑰
INQOMBQAUSQDDS-UHFFFAOYSA-N
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一般說明
碘甲烷(甲烷碘)是一种无色液体。它可通过硫酸二甲酯和浓缩KI反应来制备。据报道,碘和磷和甲醇反应也可合成碘甲烷。它和三苯基膦氯化铑(I)反应,生成铑(III)八面体配合物[RhlCl(CH3)(PPh3)2(ICH3)]。其与原子氯的气相反应动力学已过研究。该反应的绝对速率常数已有报道。
應用
碘甲烷(甲烷碘)可以用来制备稳定的中性次碘酸溶液和各种甲烷酯。
訊號詞
Danger
危險分類
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
89.8 °F - closed cup
閃點(°C)
32.1 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles
Talanta, 211, 120725-120725 (2020-02-20)
This work designs the synthesis of a novel amino morpholine schiff base functionalized calix[4]arene cage (SCC), its deposition onto Quartz Crystal Microbalance (QCM) crystal surface, and usage for the selective detecting of formaldehyde (HCHO). The SCC modified QCM sensor has
Interaction of tris (triphenylphosphine) chlororhodium (I) with iodomethane, methylallyl, and allyl chloride.
J. Chem. Soc. Sect. A, 1733-1736 (1966)
Efficient methylation of carboxylic acids with potassium hydroxide/methyl sulfoxide and iodomethane.
Synthetic Communications, 31(14), 2177-2183 (2001)
Iodomethane oxidation by dimethyldioxirane: a new route to hypoiodous acid and iodohydrines.
Organic Letters, 1(13), 2125-2128 (1999)
Absolute reaction rate of chlorine atoms with iodomethane.
Chemical Physics Letters, 268(5), 498-504 (1997)
实验方案
US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
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