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T53805

Sigma-Aldrich

三氯乙腈

98%

别名:

Trichlorocyanomethane, Tritox

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About This Item

线性分子式:
Cl3CCN
CAS号:
545-06-2
分子量:
144.39
Beilstein:
605572
EC號碼:
208-885-7
MDL號碼:
MFCD00001842
分類程式碼代碼:
12352117
PubChem物質ID:
24900271
NACRES:
NA.22

蒸汽壓力

58 mmHg ( 20 °C)

品質等級

200

化驗

98%

折射率

n20/D 1.441 (lit.)

bp

83-84 °C (lit.)

密度

1.44 g/mL at 25 °C (lit.)

SMILES 字串

ClC(Cl)(Cl)C#N

InChI

1S/C2Cl3N/c3-2(4,5)1-6

InChI 密鑰

DRUIESSIVFYOMK-UHFFFAOYSA-N

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應用

用于通过 DBU 催化的烯丙醇加成反应合成三氯乙酰亚胺酯，以及用于 MOM 催化型氮杂-Claisen 重排反应的后续研究。还可用于由二醇制备双三氯乙酰亚胺酯，再通过酸催化的环化反应生成二氢噁嗪。

象形圖

Skull and crossbonesEnvironment
GHS06,GHS09

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

165.2 °F

閃點（°C）

74 °C

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
BCCF1453
BCCB5307
WXBC7713V
WXBC7301V
WXBC5207V

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Christophe Rondot et al.
Organic letters, 9(2), 247-250 (2007-01-16)
An efficient synthesis of chiral dihydrooxazines (2) from 1-aryl-2-amino-propane-1,3-diols (1) via the corresponding bistrichloroacetimidate intermediates has been developed. In this transformation, one trichloroacetimidate acts as a leaving group and the other acts as a nucleophile. The cyclization proceeds through an
Tetrahedron, 63, 2123-2123 (2007)
Hua Zhang et al.
Journal of environmental sciences (China), 21(1), 54-61 (2009-05-01)
Dissolved organic matter (DOM) has been identified as precursor for disinfection by-products (DBPs) formation during chlorination. Recently, it has been demonstrated that the characteristics of DOM influence the DBPs formation mechanism. A study was, therefore, initiated to investigate the effects
S A Christ et al.
Journal of toxicology and environmental health, 47(3), 233-247 (1996-02-23)
Trichloroacetonitrile (TCAN) is a by-product of the chlorine disinfection of water containing natural organic material. When administered by gavage to pregnant Long-Evans rats in a medium-chain triglyceride vehicle, tricaprylin oil (Tricap), at a volume of 10 ml/kg, TCAN induced fetal
Trichloroacetonitrile.
IARC monographs on the evaluation of carcinogenic risks to humans, 71 Pt 3, 1533-1537 (1999-09-07)
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