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蒸汽密度
3.26 (vs air)
品質等級
蒸汽壓力
4.8 psi ( 20 °C)
化驗
99%
自燃溫度
905 °F
折射率
n20/D 1.387 (lit.)
bp
70-72 °C (lit.)
密度
1.223 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
COC(Cl)=O
InChI
1S/C2H3ClO2/c1-5-2(3)4/h1H3
InChI 密鑰
XMJHPCRAQCTCFT-UHFFFAOYSA-N
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應用
氯甲酸甲酯(MCF)常用于官能团的衍生化,如羧酸、胺和酚。
MCF还能用于:
MCF还能用于:
- 活化3-酰基吡啶,用于与炔基锡试剂进行亲核加成,形成2,3-二取代的1,2-二氢吡啶。
- 末端炔烃的氯酯化反应,形成β-氯-α,β-不饱和酯。
- 作为亲电试剂,介导吡啶与二烷基锂或二芳基铜酸锂的反应,生成4-取代的1,4-二氢吡啶衍生物。
- 将硝酸盐转化为甲氧基羰基硝酸盐。
訊號詞
Danger
危險分類
Acute Tox. 2 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 2
閃點(°F)
50.0 °F - closed cup
閃點(°C)
10 °C - closed cup
The First Example of Rhodium (I)-Catalyzed Regio-and Stereoselective Chloroesterification of Alkynes with Chloroformate Esters.
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Reaction of Cuprate Reagents with Pyridine in the Presence of Chloroformate. A Novel Synthesis of 1, 4-Dihydropyridine Derivatives.
Canadian Journal of Chemistry, 52(20), 3563-3564 (1974)
Regio-and chemoselective addition of alkynyltin reagents to the 2-position of 3-acylpyridines activated by methyl chloroformate: selective synthesis of 2, 3-disubstituted 1, 2-dihydropyridines.
Tetrahedron Letters, 29(15), 1785-1788 (1988)
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