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Merck

M33476

Sigma-Aldrich

2-甲基丁醛

95%

别名:

α-甲基丁醛, α-甲基正丁醛, (±)-2-甲基丁醛, 2-乙基丙醛, 2-甲基丁醛, 2-甲酰基丁烷

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About This Item

线性分子式:
C2H5CH(CH3)CHO
CAS号:
分子量:
86.13
Beilstein:
1633540
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

95%

形狀

liquid

折射率

n20/D 1.3919 (lit.)

bp

90-92 °C (lit.)

密度

0.806 g/mL at 20 °C
0.804 g/mL at 25 °C (lit.)

SMILES 字串

[H]C(=O)C(C)CC

InChI

1S/C5H10O/c1-3-5(2)4-6/h4-5H,3H2,1-2H3

InChI 密鑰

BYGQBDHUGHBGMD-UHFFFAOYSA-N

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應用

2-甲基丁醛可用作合成以下物质的反应物:
  • 在乙酸铵存在的情况下通过与各种苯乙酮和丙二腈的多组分缩合反应合成的 2-氨基-3-氰基吡啶衍生物。
  • 在氢分子存在的情况下通过与二乙胺的铑催化还原胺化反应合成的N,N-二乙基-2-甲基-1-丁胺。
  • α-采用三环非离子强路易斯碱与苯乙腈进行缩合反应合成的(2-甲基亚丁基)苯乙腈。

訊號詞

Danger

危險分類

Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

23.0 °F

閃點(°C)

-5 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Aroma extract dilution analysis (AEDA) is widely used for the screening of aroma-active compounds in gas chromatography-olfactometry (GC-O). In this study, three aroma dilution methods, (I) using different test sample volumes, (II) diluting samples, and (III) adjusting the GC injector
Paweł Mochalski et al.
Cell biochemistry and biophysics, 71(1), 323-329 (2014-08-16)
Gas chromatography with mass spectrometric detection combined with head-space needle trap extraction as the pre-concentration technique was applied to identify and quantify volatile organic compounds released or metabolised by human umbilical vein endothelial cells. Amongst the consumed species there were
C Zscheppank et al.
Analytical and bioanalytical chemistry, 406(26), 6617-6628 (2014-08-26)
A new method for the growth-dependent headspace analysis of bacterial cultures by needle trap (NT)-gas chromatography-mass spectrometry (GC-MS) was established. NTs were used for the first time as enrichment technique for volatile organic compounds (VOCs) in the headspace of laboratory

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