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蒸汽密度
4 (vs air)
品質等級
蒸汽壓力
<1 mmHg ( 20 °C)
化驗
99%
形狀
liquid
expl. lim.
6.9 %
折射率
n20/D 1.423 (lit.)
bp
166 °C (lit.)
密度
0.931 g/mL at 25 °C (lit.)
SMILES 字串
CC(=O)CC(C)(C)O
InChI
1S/C6H12O2/c1-5(7)4-6(2,3)8/h8H,4H2,1-3H3
InChI 密鑰
SWXVUIWOUIDPGS-UHFFFAOYSA-N
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一般說明
4-羟基-4-甲基-2-戊酮通常作为溶剂在各种工业中使用，包括油漆、涂料、胶粘剂和印刷油墨。
應用
4-羟基-4-甲基-2-戊酮可用于合成以下物质：
也可作为络合剂，通过与金属盐(MX)和氰基金属化物反应合成双金属氰化物(DMC)催化剂。
- 二醇单酯，通过串联醇醛转移Tischtschenko反应与醛类反应，以三甲基铝作为催化剂。
- 醇醛转移产物，例如β-羟基酮，通过与各种醛类反应，以L-脯氨酸作为催化剂。
- 单-α-芳化酮和酯类，分别与芳基卤化物和芳基三氟化物发生Pd催化反应。
也可作为络合剂，通过与金属盐(MX)和氰基金属化物反应合成双金属氰化物(DMC)催化剂。
訊號詞
Warning
危險分類
Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
136.4 °F - closed cup
閃點（°C）
58 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
I Magneron et al.
Environmental science & technology, 37(18), 4170-4181 (2003-10-04)
The OH-initiated oxidation of two VOCs directly emitted to the atmosphere through their use as industrial solvents, hexylene glycol (HG, (CH3)2C(OH)CH2CH(OH)CH3) and diacetone alcohol (DA, (CH3)2C(OH)CH2C(O)CH3), has been studied in two photoreactors: a 140 L Teflon bag irradiated by lamps
Molecular probes of the mechanism of cytochrome P450. Oxygen traps a substrate radical intermediate.
Harriet L R Cooper et al.
Archives of biochemistry and biophysics, 507(1), 111-118 (2010-11-16)
The diagnostic substrate tetramethylcyclopropane (TMCP) has been reexamined as a substrate with three drug- and xenobiotic-metabolizing cytochrome P450 enzymes, human CYP2E1, CYP3A4 and rat CYP2B1. The major hydroxylation product in all cases was the unrearranged primary alcohol along with smaller
Tandem aldol-transfer-Tischtschenko reaction of aldehydes and ?-hydroxyketones catalyzed by trimethylaluminum
Simpura I and Nevalainen V
Tetrahedron Letters, 42(23), 3905-3907 (2001)
Synthesis of Polycarbonate Polyols by Double-Metal Cyanide Catalyzed Copolymerization of Epoxide with Carbon Dioxide
Lim J, et al.
Journal of Nanoscience and Nanotechnology, 17(10), 7507-7514 (2017)
S Chandrasekhar et al.
Chemical communications (Cambridge, England), (21)(21), 2450-2451 (2004-10-30)
We demonstrate for the first time, L-proline as a chiral catalyst for transfer aldol reaction between aldehydes and diacetone alcohol.
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