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Merck

D77001

Sigma-Aldrich

己二腈

99%

别名:

1,6-hexanedinitrile, ADN, 1,4-二氰基丁烷

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About This Item

线性分子式:
NC(CH2)4CN
CAS号:
分子量:
108.14
Beilstein:
1740005
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3.7 (vs air)

品質等級

蒸汽壓力

0.01 mmHg ( 40 °C)

化驗

99%

形狀

liquid

自燃溫度

1022 °F

expl. lim.

4.99 %

折射率

n20/D 1.438 (lit.)

bp

295 °C (lit.)

mp

1-3 °C (lit.)

密度

0.951 g/mL at 25 °C (lit.)

SMILES 字串

N#CCCCCC#N

InChI

1S/C6H8N2/c7-5-3-1-2-4-6-8/h1-4H2

InChI 密鑰

BTGRAWJCKBQKAO-UHFFFAOYSA-N

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應用

己二腈是制造尼龙-6,6的关键前体。 它可以进行催化氢化以形成六亚甲基二胺(HMD)。 由于其高阳极和热稳定性,ADN非常有潜力作为高压锂电池中电解质溶液的溶剂。

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

325.4 °F - closed cup

閃點(°C)

163 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Inhalation toxicity of adiponitrile in rats.
L W Smith et al.
Toxicology and applied pharmacology, 65(2), 257-263 (1982-09-15)
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ChemSusChem, 5(4), 617-620 (2012-03-24)
Current affairs: Adiponitrile, used to produce nylon 6.6, is prepared from the renewable compound glutamic acid by an electrochemical route, involving electro-oxidative decarboxylation and Kolbe coupling reactions. The new route is an example of the use of glutamic acid as
F R Johannsen et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 7(1), 33-40 (1986-07-01)
Acetonitrile (ACN), adiponitrile (ADN), and propionitrile (PN), were evaluated for embryotoxic and teratogenic potential in rats. Mated Sprague-Dawley rats were administered one of the three nitriles by gavage on gestation Days 6-19, inclusive. Daily dosage levels (mg/kg body wt) were:
Soo-Jin Yeom et al.
The Biochemical journal, 415(3), 401-407 (2008-04-17)
Nitrilase from Rhodococcus rhodochrous ATCC 33278 hydrolyses both aliphatic and aromatic nitriles. Replacing Tyr-142 in the wild-type enzyme with the aromatic amino acid phenylalanine did not alter specificity for either substrate. However, the mutants containing non-polar aliphatic amino acids (alanine
Electrolyte formulations based on dinitrile solvents for high voltage Li-ion batteries.
Duncan H, et al.
Journal of the Electrochemical Society, 160(6), A838-A848 (2013)

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