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Merck

538264

Sigma-Aldrich

丁腈

≥99%

别名:

丙基氰

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About This Item

线性分子式:
CH3CH2CH2CN
CAS号:
分子量:
69.11
Beilstein:
1361452
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

2.4 (vs air)

蒸汽壓力

23 mmHg ( 25 °C)

化驗

≥99%

自燃溫度

910 °F

折射率

n20/D 1.384 (lit.)

bp

115-117 °C (lit.)

mp

−112 °C (lit.)

溶解度

DMF: miscible(lit.)
alcohol: miscible(lit.)
diethyl ether: miscible(lit.)
water: very slightly soluble(lit.)

密度

0.794 g/mL at 25 °C (lit.)

官能基

nitrile

SMILES 字串

CCCC#N

InChI

1S/C4H7N/c1-2-3-4-5/h2-3H2,1H3

InChI 密鑰

KVNRLNFWIYMESJ-UHFFFAOYSA-N

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一般說明

丁腈(丙腈,BN)是一种线性氰化物。采用气相沉积法制备了丁腈 (BN) 玻璃。研究了氮化硼玻璃的摩尔体积与沉积温度的关系。其与高温水(温度 = 330℃,压力范围 = 128-2600 bar)反应生成丁酰胺、丁酸和氨。在 LiOH 促进的钴基 Raney 催化剂存在下发生选择性还原,得到 n -丁胺。

應用

丁腈适合用于研究立体化学因素对价间电荷转移 (IT) 的影响。它可用于染料敏化太阳能电池的电解质组成。

象形圖

FlameSkull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

71.6 °F

閃點(°C)

22 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Slide 1 of 1

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Stereochemical influences on intervalence charge transfer in homodinuclear complexes of ruthenium.
D M D'Alessandro et al.
Inorganic chemistry, 40(26), 6841-6844 (2001-12-12)
Tailoring Raney-catalysts for the selective hydrogenation of butyronitrile to n-butylamine.
Chojecki A, et al.
J. Catal., 245(1), 237-248 (2007)
Effect of pressure on the rate of butyronitrile hydrolysis in high-temperature water.
Iyer SD and Klein MT.
Journal of Supercritical Fluids, 10(3), 191-200 (1997)
Frédéric Sauvage et al.
Journal of the American Chemical Society, 133(33), 13103-13109 (2011-06-28)
We elaborated a new electrolyte composition, based on butyronitrile solvent, that exhibits low volatility for use in dye-sensitized solar cells. The strong point of this new class of electrolyte is that it combines high efficiency and excellent stability properties, while
Hideyuki Nakayama et al.
The journal of physical chemistry. B, 117(35), 10311-10319 (2013-08-08)
Molar volumes (Vm) of vapor-deposited ethylcyclohexane (ECH) and butyronitrile (BN, sometimes called butanenitrile) glasses were studied as a function of deposition temperature (Td). ECH glasses deposited at Td sufficiently below their glass-transition temperature (Tg) exhibited changes in Vm on heating

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