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Merck

B80100

Sigma-Aldrich

2-溴吡啶

99%

别名:

α-溴氮杂苯, β-溴吡啶, 2-溴吡, 邻溴吡啶

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About This Item

经验公式(希尔记法):
C5H4BrN
CAS号:
分子量:
158.00
Beilstein:
105789
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

liquid

折射率

n20/D 1.572 (lit.)

bp

192-194 °C (lit.)

密度

1.657 g/mL at 25 °C (lit.)

SMILES 字串

Brc1ccccn1

InChI

1S/C5H4BrN/c6-5-3-1-2-4-7-5/h1-4H

InChI 密鑰

IMRWILPUOVGIMU-UHFFFAOYSA-N

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一般說明

2-溴吡啶是一种有机化合物,广泛用作 有机合成中的合成砌块。它还用作 合成吡啶衍生物的中间体。

應用

2-溴吡啶可用作:
  • 通过各种交叉偶联反应形成C−N键的合成砌块。
  • 通过钯催化与卤代芳烃进行Negishi交叉偶联反应的反应剂。
  • 在存在铜的条件下,用作催化合成2′-吡啶二氟乙酸乙酯的反应剂。

象形圖

Skull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

195.1 °F - closed cup

閃點(°C)

90.6 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis of solid 2-pyridylzinc reagents and their application in Negishi reactions.
Colombe JR, et al.
Organic Letters, 15(22), 5754-5757 (2013)
Nicolas Großmann et al.
Dalton transactions (Cambridge, England : 2003), 45(45), 18365-18376 (2016-11-05)
Recently, research has revealed that molecules can be used to steer the local spin properties of ferromagnetic surfaces. One possibility to manipulate ferromagnetic-metal-molecule interfaces in a controlled way is to synthesize specific, non-magnetic molecules to obtain a desired interaction with
Amino acid promoted CuI-catalyzed C-N bond formation between aryl halides and amines or N-containing heterocycles.
Zhang H, et al.
The Journal of Organic Chemistry, 70(13), 5164-5173 (2005)
A Versatile and Efficient Ligand for Copper-Catalyzed Formation of C-N, C-O, and P-C Bonds: Pyrrolidine-2-Phosphonic Acid Phenyl Monoester.
Rao H, et al.
Chemistry?A European Journal , 12(13), 3636-3646 (2006)
Long Xu et al.
Journal of lipid research, 61(4), 560-569 (2020-02-08)
This article focuses on the establishment of an accurate and sensitive quantitation method for the analysis of furan fatty acids. In particular, the sensitivity of GC/MS and UPLC/ESI/MS/MS was compared for the identification and quantification of furan fatty acids. Different

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