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Merck

A70704

Sigma-Aldrich

(1R,2R)-(-)-2-氨基-1-(4-硝基苯基)-1,3-丙二醇

99%

别名:

D-(-)-苏-1-对硝基苯基-2-氨基-1,3-丙二醇, 氯霉素碱

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About This Item

线性分子式:
HOCH2CH(NH2)CH(C6H4NO2)OH
CAS号:
分子量:
212.20
EC號碼:
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

powder

光學活性

[α]25/D −30°, c = 1 in 6 M HCl

mp

163-165 °C (lit.)

SMILES 字串

N[C@H](CO)[C@H](O)c1ccc(cc1)[N+]([O-])=O

InChI

1S/C9H12N2O4/c10-8(5-12)9(13)6-1-3-7(4-2-6)11(14)15/h1-4,8-9,12-13H,5,10H2/t8-,9-/m1/s1

InChI 密鑰

OCYJXSUPZMNXEN-RKDXNWHRSA-N

應用

(1R,2R)-(-)-2-氨基-1-(4-硝基苯基)-1,3-丙二醇可用于通过NN-二甲基化,制备(1R,2R)-(-)-2-二甲基氨基-1-(4-硝基苯基)-1,3-丙二醇。 它也可以用作合成原料,对(1R,2R)-1,3-二乙酰氧基-1-(4-硝基苯基)-2-丙基异硫氰酸酯[(RR)-DANI]进行合成。

象形圖

Exclamation mark

訊號詞

Warning

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Development of new isothiocyanate-based chiral derivatizing agent for amino acids.
Peter M, et al.
Chromatographia, 50(5-6), 373-375 (1999)
(1R, 2R)-(-)-2-Dimethylamino-1-(4-nitrophenyl)-1, 3-propanediol/l-proline cocatalyzed enantioselective Morita-Baylis-Hillman reaction.
Tang H, et al.
Catalysis Communications, 8(11), 1811-1814 (2007)
W A Korfmacher et al.
Journal of chromatographic science, 28(5), 236-238 (1990-05-01)
The thermospray (TS) liquid chromatographic-mass spectrometric analysis of the antibiotic chloramphenicol and three related compounds is presented. The three additional compounds are dehydrochloramphenicol, aminodehydrochloramphenicol, and nitrophenylaminopropanediol. Baseline separation of the four compounds is achieved. The TS mass spectrum of each
Induced synthesis of phosphatases in Anacystis nidulans by p-NO2-phenylserinal.
M L Muñoz-Calvo et al.
The Journal of antibiotics, 33(5), 520-522 (1980-05-01)
D K Zheng et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 25(6), 430-434 (1990-01-01)
Threo (-) or (+)-1-(p-nitrophenyl)-1,3-dihydroxypropylamine-2 was found to be a useful resolving agent for racemic gossypol. The optical and chemical stability of the condensate of enantiomeric gossypols with the titled amine and the great difference in the Rf values on TLC

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