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Merck

96662

Sigma-Aldrich

三己基十四烷化膦溴化物

≥95%

别名:

十四烷基三己基溴化膦

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About This Item

线性分子式:
[CH3(CH2)5]3P(Br)(CH2)13CH3
分子量:
563.76
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥95%
≥95.0% (T)

形狀

solid

密度

0.96 g/mL at 20 °C (lit.)

SMILES 字串

[Br-].CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C32H68P.BrH/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;/h5-32H2,1-4H3;1H/q+1;/p-1

InChI 密鑰

RJELOMHXBLDMDB-UHFFFAOYSA-M

應用

三己基十四烷化膦溴化物是一种膦基离子液体,可作为可循环利用的反应培养基,用于 Heck 交叉偶联反应。它也可用于制备支撑液膜(SLM),用于气体分离过程。
用于以下反应的反应物:
  • 通过无溶剂阴离子复分解反应制备离子液体
  • 制备钨磷酸盐四烷基膦和异钨酸林德奎斯特簇阴离子

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Heck reactions of aryl halides in phosphonium salt ionic liquids: library screening and applications.
Gerritsma DA, et al.
Tetrahedron Letters, 45(41), 7629-7631 (2004)
Gas separation properties of supported liquid membranes prepared with unconventional ionic liquids.
Cserjesi P, et al.
Journal of Membrane Science, 349(1), 6-11 (2010)
Guokai Cui et al.
Chemistry, an Asian journal, 12(21), 2863-2872 (2017-08-26)
A new strategy involving the computer-assisted design of substituted imidazolate-based ionic liquids (ILs) through tuning the absorption enthalpy as well as the basicity of the ILs to improve SO
Sarah F R Taylor et al.
Physical chemistry chemical physics : PCCP, 19(22), 14306-14318 (2017-05-26)
This study reports on understanding the formation of bubbles in ionic liquids (ILs), with a view to utilising ILs more efficiently in gas capture processes. In particular, the impact of the IL structure on the bubble sizes obtained has been
Guokai Cui et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(14), 5632-5639 (2015-02-18)
A new approach has been developed to improve SO2 sorption by cyano-containing ionic liquids (ILs) through tuning the basicity of ILs and cyano-sulfur interaction. Several kinds of cyano-containing ILs with different basicity were designed, prepared, and used for SO2 capture.

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