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Merck

938742

Sigma-Aldrich

RuPhos Pd G6 Br

greener alternative

别名:

(RuPhos)Pd(p-CF3C6H4)(Br), 2-Dicyclohexylphosphino-2′,6′-diisopropoxybiphenyl Pd G6 Br

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About This Item

经验公式(希尔记法):
C37H47BrF3O2PPd
分子量:
798.06
分類程式碼代碼:
12352100
NACRES:
NA.21

形狀

powder

品質等級

反應適用性

reaction type: Cross Couplings
reagent type: catalyst

環保替代產品特色

Catalysis
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sustainability

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顏色

very faintly yellow

官能基

phosphine

環保替代類別

SMILES 字串

Br[Pd](C1=CC=C(C=C1)C(F)(F)F)P(C2=C(C3=C(C=CC=C3OC(C)C)OC(C)C)C=CC=C2)(C4CCCCC4)C5CCCCC5

InChI

InChI=1S/C30H43O2P.C7H4F3.BrH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;8-7(9,10)6-4-2-1-3-5-6;;/h11-13,18-25H,5-10,14-17H2,1-4H3;2-5H;1H;/q;;;+1/p-1

InChI 密鑰

IYBINOQILDORLG-UHFFFAOYSA-M

相关类别

一般說明

RuPhos Pd G6 is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

特點和優勢

For feature and benefits, please visit the technical article on Buchwald G6 Precatalysts.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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