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Merck

933708

Sigma-Aldrich

Lithium difluorophosphate

new

≥99% trace metals basis, acid ≤ 200 ppm, battery grade

别名:

LiDFP, LiF2PO2, Lithium difluorophosphinate, Lithium phosphorodifluoridate

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About This Item

经验公式(希尔记法):
LiPO2F2
CAS号:
分子量:
107.91
分類程式碼代碼:
12161900

等級

battery grade

品質等級

描述

acid ≤ 200 ppm

化驗

≥99% trace metals basis

形狀

powder

雜質

≤200 ppm acid

正離子痕跡

Ca: ≤5 ppm
Cr: ≤10 ppm
Fe: ≤5 ppm
K: ≤5 ppm
Na: ≤5 ppm
Pb: ≤5 ppm

應用

battery manufacturing

一般說明

Lithium difluorophosphate (LiDFP) is a high-performance additive for lithium-ion batteries. LiDFP is a white powder that is soluble in acetone and dimethoxyethane and slightly soluble (0.4g/100g solvent) in both diethyl carbonate and 1:1 v/v mixtures of dimethylcarbonate and propylene carbonate. Our LiDFP is designed with high-purity and low trace impurities of moisture and acid

應用

Lithium difluorophosphate is a multi-functional additive for high voltage lithium-ion batteries and is often added to lithium hexafluorophosphate (LiPF6)-based electrolytes in carbonate solvents. For example, a recent study showed that a 1 wt% addition of LiDFP to the LiPF6-carbonate electrolyte in a NMC-graphite cell significantly increased capacity retention (97%) after 200 cycles, compared to the same cells without the additive (only 77% capacity retention.)[1] LiDFP has been shown to perform well with nickel-rich cathode materials[2] because it generates a more uniform, extremely stable, and lower resistance solid-electrolyte interphase (SEI) on the cathode surface. This passivation film not only suppresses the subsequent decomposition of the electrolyte, but also prevents the dissolution of transition metal ions from NMC particles, resulting in improved cyclic stability and discharge capacity. In addition, research suggests that LiDPF additive also helps to form a stable and ionically conductive SEI passivation film on lithium metal anodes.[3] Our LiDFP, with high-purity and low moisture and acid impurities, is suitable for research on increasing the energy density and longer cycling performance in lithium-ion batteries and lithium-metal batteries.

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说明
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訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3


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?Additive engineering for robust interphases to stabilize high-Ni layered structures at ultra-high voltage of 4.8?V
Tan, S., Shadike, Z., Li, J.?et al.
Nature Energy, 7, 484?494-484?494 (2022)
Lithium difluorophosphate as a multi-functional electrolyte additive for 4.4V LiNi0.5Co0.2Mn0.3O2/graphite lithium ion batteries
Lei, Qiufen, et al.
Journal of Electroanalytical Chemistry, 846, 113141-113141 (2019)

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