917745

[Ni(dtbbpy)(H₂O)₄]Cl₂

• 别名: Nickel(2+), tetraaqua[4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-κN1,κN1′]-, chloride
• 经验公式（希尔记法）: C₁₈H₃₂Cl₂N₂NiO₄
• CAS号: 2035424-75-8
• 分子量: 470.06
• 分類程式碼代碼: 12161600
• NACRES: NA.22

属性

• 形狀: powder
• 品質等級: 100
• 反應適用性: reagent type: catalyst; reaction type: Cross Couplings
• mp: >300 °C

说明

應用

[Ni(dtbbpy)(H₂O)₄]Cl₂ is a Ni precatalyst used in a series of Ni/photoredox dual catalysis cross-coupling reactions. These transformations include the decarboxylative coupling of oxetanyl amino acids with aryl halides.

其他說明

Dual Photoredox/Nickel-Catalyzed Conversion of Aryl Halides to Aryl Aminooxetanes: Computational Evidence for a Substrate-Dependent Switch in Mechanism

1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable