跳转至内容
Merck
所有图片(2)

Key Documents

View All Documentation

901409

Sigma-Aldrich

[铱 (dF (Me) ppy)] 2 (dtbbpy) ] PF 6

别名:

铱 (III) 双 [2-（2,4-二氟苯基）-5-甲基吡啶- N ,C 20 ]-4,40-二- 叔 -丁基-2,20-二吡啶六氟磷酸盐

登录查看公司和协议定价
所有图片(2)

About This Item

经验公式（希尔记法）:
C42H40F10IrN4P
CAS号:
1335047-34-1
分子量:
1013.97
分類程式碼代碼:
12161600
NACRES:
NA.22

形狀

solid

品質等級

100

反應適用性

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

活化光觸媒

450 nm

相关类别

應用

[Ir (dF (Me) ppy)] 2 (dtbbpy) ] PF 6 是一种光催化剂，容易促进烯烃的加氢胺化反应，也容易促进羧酸的脱羧芳基化反应和乙烯基化反应（通过金属卟啉催化）。

产品可与我们的光反应器系列一起使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

其他說明

仲烃胺催化未活化烯烃的分子间氢化反应

光还原与镍催化的结合：羧酸与卤化乙烯的脱羧交叉偶联

含芳基三唑环金属配体的增强发光铱 (III) 配合物

二芳基硼酸和光还原组合催化的碳水化合物 C-H 烷基化反应

相關產品

产品编号
说明
价格

747769

[Ir(dtbbpy)(ppy)2]PF6

747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

804215

[Ir{dFCF3ppy}2（bpy）]PF6

900540

Ir(dFppy)3

900539

铱 [ p -F (t-Bu)-ppy] 3

900538

Ir(p-F-ppy)3

900570

Ir[dF(t-Bu)-ppy]3

901368

[Ir(dFppy)2(dtbbpy)]PF6

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%

904694

Ir(p-CF3-ppy)3, ≥95%

905518

Ir(dFFppy)2(dtbbpy)PF6

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

925497

[Ir(dFOMeppy)2(dtbbpy)]PF6, ≥95%

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
MKCJ5323
MKCK6936

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S, et al.
European Journal of Inorganic Chemistry, 2013(30), 5329-5343 (2013)
Andrew J Musacchio et al.
Science (New York, N.Y.), 355(6326), 727-730 (2017-02-18)
The intermolecular hydroamination of unactivated alkenes with simple dialkyl amines remains an unsolved problem in organic synthesis. We report a catalytic protocol for efficient additions of cyclic and acyclic secondary alkyl amines to a wide range of alkyl olefins with
Correlating electronic structures to electrochemiluminescence of cationic Ir complexes.
Swanick KN, et al.
Royal Society of Chemistry Advances, 43, 19961-19964 (2013)
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple
Sébastien Ladouceur et al.
Inorganic chemistry, 50(22), 11514-11526 (2011-10-04)
Herein we report the synthesis of 4-aryl-1-benzyl-1H-1,2,3-triazoles (atl), made via "Click chemistry" and their incorporation as cyclometallating ligands into new heteroleptic iridium(III) complexes containing diimine (N(^)N) ancillary ligands 2,2'-bipyridine (bpy) and 4,4'-di-tert-butyl-2,2'-bipyridine (dtBubpy). Depending on decoration, these complexes emit from
查看所有相关文献

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门