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品質等級
化驗
≥97%
形狀
powder or crystals
反應適用性
reagent type: catalyst
reaction type: Photocatalysis
mp
171 °C
活化光觸媒
400 nm
SMILES 字串
C1(C=CC(C2=CC=C(C3=CC=CC=C3)C=C2)=C4)=C4OC(C=C(C5=CC=C(C6=CC=CC=C6)C=C5)C=C7)=C7N1C8=C(C=CC=C9)C9=CC=C8
應用
该二氢吩嗪基有机光氧化还原催化剂（除二氢吩嗪催化剂901112外）被设计为一种强激发态还原剂，并具有高级的光物理和电化学性能，使其能够用作钌或铱基光氧化还原催化剂的可持续替代品。例如，在光氧化还原催化的原子转移自由基聚合（ATRP）的应用中，二氢吩嗪和吩恶嗪衍生物被证明可替代钌或铱配合物，以控制聚合物的合成和小分子转化，例如三氟甲基化、原子转移自由基的加成和双镍/光氧化还原催化的CN和CS交叉偶联。在与Miyake 研究小组的合作中，采用了二氢吩嗪和苯恶嗪基有机光氧化还原催化剂。
产品可以和我们的 光反应器系列一起使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）
产品可以和我们的 光反应器系列一起使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）
其他說明
法律資訊
专利申请PCT/US2016/058245。与New Iridium Inc.合作出售。如需大于25克的订单，请通过chern@newiridium.com与New Iridium联系，或访问https://www.newiridium.com。
Phenox O-PC is a trademark of New Iridium LLC
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
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Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts.
Pearson, et al.
Journal of the American Chemical Society, 138, 11399-11407 (2017)
Jordan C Theriot et al.
Science (New York, N.Y.), 352(6289), 1082-1086 (2016-04-02)
Atom transfer radical polymerization (ATRP) has become one of the most implemented methods for polymer synthesis, owing to impressive control over polymer composition and associated properties. However, contamination of the polymer by the metal catalyst remains a major limitation. Organic
Ya Du et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(46), 10962-10968 (2017-06-28)
Photoredox catalysis is a versatile approach for the construction of challenging covalent bonds under mild reaction conditions, commonly using photoredox catalysts (PCs) derived from precious metals. As such, there is need to develop organic analogues as sustainable replacements. Although several
Ryan M Pearson et al.
Journal of the American Chemical Society, 138(35), 11399-11407 (2016-08-25)
N-Aryl phenoxazines have been synthesized and introduced as strongly reducing metal-free photoredox catalysts in organocatalyzed atom transfer radical polymerization for the synthesis of well-defined polymers. Experiments confirmed quantum chemical predictions that, like their dihydrophenazine analogs, the photoexcited states of phenoxazine
Chern-Hooi Lim et al.
Journal of the American Chemical Society, 139(1), 348-355 (2016-12-16)
Photoexcited intramolecular charge transfer (CT) states in N,N-diaryl dihydrophenazine photoredox catalysts are accessed through catalyst design and investigated through combined experimental studies and density functional theory (DFT) calculations. These CT states are reminiscent of the metal to ligand charge transfer
商品
Photoredox catalysis is a powerful synthetic methodology to form challenging covalent bonds using light irradiation. It is effective for light-driven polymer and small molecule synthesis.
Photoredox catalysis is a powerful synthetic methodology to form challenging covalent bonds using light irradiation. It is effective for light-driven polymer and small molecule synthesis.
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