推荐产品
蒸汽壓力
1 mmHg ( 621 °C)
形狀
turnings
自燃溫度
950 °F
成份
anhydrous tetrahydrofuran, 37.5 mmol
反應適用性
reagent type: reductant
電阻係數
4.46 μΩ-cm, 20°C
bp
1090 °C (lit.)
mp
648 °C (lit.)
密度
1.74 g/mL at 25 °C (lit.)
SMILES 字串
[Mg]
InChI
1S/Mg
InChI 密鑰
FYYHWMGAXLPEAU-UHFFFAOYSA-N
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應用
Magnesium turnings (Mg) can be used to prepare reactive organomagnesium compounds (Grignard reagents, GR) by reacting with alkyl, allyl, vinyl, or aryl halides. These GR reagents are widely used in organic synthesis to produce useful chemical intermediates. Mg can also be used to prepare tetraisopropyl- and tetrabutyl-distibane by dehalogenation of diisopropyl- and dibutyl-antinomy bromide, respectively.
其他說明
产品为制备的有机镁试剂的 0.5M 溶液,40% 顶空。
法律資訊
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Self-heat. 1 - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類(WGK)
WGK 1
閃點(°F)
1.4 °F - closed cup
閃點(°C)
-17.0 °C - closed cup
Titanium-magnesium-assisted scission of 1, 4-bis (trimethylsilyl)-1, 3-butadiyne: synthesis and structure of a titanium (III) tweezer complex,[(. eta. 5-C5HMe4) 2Ti (. eta. 1-C. tplbond. CSiMe3) 2][Mg (THF) Cl]
Organometallics, 12(7), 2820-2824 (1993)
Mechanical activation of magnesium turnings for the preparation of reactive Grignard reagents
The Journal of Organic Chemistry, 56(2), 698-703 (1991)
Reduktion von isopropyl-und butylantimonbromiden mit magnesium
Journal of Organometallic Chemistry, 186(1), C5-C8 (1980)
Proceedings of the National Academy of Sciences of the United States of America, 110(49), 19737-19741 (2013-11-20)
Northern Hemisphere sea ice has been declining sharply over the past decades and 2012 exhibited the lowest Arctic summer sea-ice cover in historic times. Whereas ongoing changes are closely monitored through satellite observations, we have only limited data of past
Nature chemistry, 5(7), 613-620 (2013-06-22)
The development of nanocarriers that selectively release guest molecules on sensing a particular biological signal is being actively pursued in nanomedicine for diagnostic and therapeutic purposes. Here we report a protein-based nanocarrier that opens in the presence of intracellular adenosine-5'-triphosphate
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