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Merck

695904

Sigma-Aldrich

1,3-丁二烯 溶液

15 wt. % in hexane

别名:

Bivinyl, Vinylethylene, alpha,gamma-Butadiene

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About This Item

经验公式(希尔记法):
C4H6
CAS号:
分子量:
54.09
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

形狀

liquid

品質等級

濃度

15 wt. % in hexane

折射率

n20/D 1.376

密度

0.682 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

C=CC=C

InChI

1S/C4H6/c1-3-4-2/h3-4H,1-2H2

InChI 密鑰

KAKZBPTYRLMSJV-UHFFFAOYSA-N

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應用

1,3-Butadiene can be used as a monomer to synthesize polybutadiene with one hydroxy end group and other silyl hydroxy-protecting end group, a precursor for two-step synthesis of hydroxyl-terminated polybutadiene (HTPB).

訊號詞

Danger

危險分類

Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Muta. 1B - Repr. 2 - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3

標靶器官

Central nervous system, Nervous system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

-105.0 °F

閃點(°C)

-76.11 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Synthesis of hydroxyl-terminated polybutadiene bearing pendant carboxyl groups by combination of anionic polymerization and blue light photocatalytic thiol-ene reaction and its pH-triggered self-assemble behavior.
Zhang W, et al.
Reactive and Functional Polymers, 127, 161-167 (2018)
Xin Min et al.
Royal Society open science, 5(5), 180156-180156 (2018-06-13)
A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structure of HTPB was characterized and verified by FTIR and
Dewakar Sangaraju et al.
Analytical chemistry, 84(3), 1732-1739 (2012-01-10)
1,3-Butadiene (BD) is an important industrial chemical and a common environmental pollutant present in urban air. BD is classified as a human carcinogen based on epidemiological evidence for an increased incidence of leukemia in workers occupationally exposed to BD and
Mohammed Bahou et al.
The Journal of chemical physics, 137(8), 084310-084310 (2012-09-04)
The reactions of chlorine and hydrogen atoms with trans-1,3-butadiene in solid para-hydrogen (p-H(2)) were investigated with infrared (IR) absorption spectra. When a p-H(2) matrix containing Cl(2) and trans-1,3-butadiene was irradiated with ultraviolet light at 365 nm, intense lines at 650.3
R I Kaiser et al.
The journal of physical chemistry. A, 116(17), 4248-4258 (2012-04-14)
The crossed beam reactions of the phenyl radical (C(6)H(5), X(2)A(1)) with 1,3-butadiene (C(4)H(6), X(1)A(g)) and D6-1,3-butadiene (C(4)D(6), X(1)A(g)) as well as of the D5-phenyl radical (C(6)D(5), X(2)A(1)) with 2,3-D2-1,3-butadiene and 1,1,4,4-D4-1,3-butadiene were carried out under single collision conditions at collision

实验方案

2-Butene; 2-Methylbutane; 1,3-Butadiene; Propyne

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