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品質等級
化驗
97%
形狀
solid
mp
121-124 °C
SMILES 字串
C[Si](C)(C)N([Mg]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
InChI
1S/2C6H18NSi2.Mg/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2
InChI 密鑰
WYPTZCBYSQFOQS-UHFFFAOYSA-N
應用
双(六甲基二硅氮化物)镁是合成 rac -丙交酯大范围配基配合物的重要前体。 也可用于合成 ItBu:Mg[N(SiMe3)2]2,其中 I t Bu =(1,3-二- 叔 -丁基咪唑-2-亚基),该催化剂用于碳化二亚胺加胺的鸟苷酸化反应。
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
安全危害
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Stereoselectivity switch between zinc and magnesium initiators in the polymerization of rac-lactide: different coordination chemistry, different stereocontrol mechanisms.
Macromolecules, 47(22), 7750-7764 (2014)
Lactide polymerization catalyzed by Mg and Zn diketiminate complexes with flexible ligand frameworks.
Dalton Transactions, 43(17), 6339-6352 (2014)
Catalytic C?N bond formation in guanylation reaction by N-heterocyclic carbene supported magnesium (II) and zinc (II) amide complexes.
Journal of Organometallic Chemistry, 769, 112-118 (2014)
Highly active magnesium initiators for ring-opening polymerization of rac-lactide.
Macromolecules, 43(16), 6535-6537 (2010)
Nanoscale, 10(26), 12526-12534 (2018-06-23)
Magnesium secondary batteries are promising candidates for large-scale energy storage systems with high safety, because of the dendrite-free electrodeposition of the magnesium anode. However, the search for available cathode materials remains a significant challenge, hindering their development. In this work
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