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Merck

667846

Sigma-Aldrich

Poly(benzimidazobenzophenanthroline)

别名:

BBL

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About This Item

线性分子式:
(C20H6N4O2)n
CAS号:
MDL號碼:
分類程式碼代碼:
12352103
NACRES:
NA.23

描述

Band gap: 1.9 eV

形狀

solid

軌道能量

HOMO -5.9 eV 
LUMO -4.0 eV 

OPV器件效能

ITO/MEH-PPV/BBL/Al

  • Short-circuit current density (Jsc): 1.98 mA/cm2
  • Open-circuit voltage (Voc): 0.93 V
  • Fill Factor (FF): 0.47
  • Power Conversion Efficiency (PCE): 1.1 %

ITO/PPV/BBL/Al
  • Short-circuit current density (Jsc): 2.15 mA/cm2
  • Open-circuit voltage (Voc): 1.1 V
  • Fill Factor (FF): 0.5
  • Power Conversion Efficiency (PCE): 1.5 %

半導體屬性

N-type (mobility=0.1 cm2/V·s)
P-type (mobility=0.4 cm2/V·s)

相关类别

應用

在有机场效应晶体管 (FET) 和光伏电池 (PV) 中具有 n 型行为的聚合物半导体。在甲磺酸中从溶液中加工。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


分析证书(COA)

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Jenekhe, S.A.; Yi, S.
Applied Physics Letters, 77, 2635-2635 (2000)
Amit Babel et al.
Journal of the American Chemical Society, 125(45), 13656-13657 (2003-11-06)
Field-effect mobility of electrons as high as 0.1 cm2/(V s) is observed in n-channel thin film transistors fabricated from a solution spin-coated conjugated ladder polymer, poly(benzobisimidazobenzophenanthroline) (BBL), under ambient air conditions. This is the highest electron mobility observed to date
Efficient Solar Cells from Layered Nanostructures of Donor and Acceptor Conjugated Polymers
Alam, M. M.; Jenekhe, S. A.
Chemistry of Materials, 16, 4647-4656 (2004)
Manoj, A.G.; Narajan, K.S.
Opt. Mater., 21, 417-417 (2002)

商品

Organic polymer semiconductors are key materials for research in organic electronics. Efforts to develop field-effect transistors (FETs), plastic solar cells, organic RFIDs, and electrochemical sensors all depend on availability of reliable organic semiconductors with choices of different molecular architectures and consistent quality. Sigma-Aldrich is pleased to offer these conjugated polymer semiconductors.

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

Intrinsically stretchable active layers for organic field-effect transistors (OFET) are discussed. Polymer structural modification & post-polymerization modifications are 2 methods to achieve this.

Fabrication procedure of organic field effect transistor device using a soluble pentacene precursor.

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