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Merck

568600

Sigma-Aldrich

6-(马来酰亚胺基)己酸琥珀酰亚胺酯

98%

别名:

6-马来酰亚氨基己酸 N-琥珀酰亚胺酯, N-(ε-马来酰亚胺己酰氧)琥珀酰亚胺, N-琥珀酰亚胺 6-马来酰亚胺己酸酯, EMCS

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About This Item

经验公式(希尔记法):
C14H16N2O6
CAS号:
分子量:
308.29
Beilstein:
1499815
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

反應適用性

reagent type: cross-linking reagent

mp

70-73 °C (lit.)

官能基

NHS ester
imide
maleimide

儲存溫度

−20°C

SMILES 字串

O=C(ON(C(CC1)=O)C1=O)CCCCCN2C(C=CC2=O)=O

InChI

1S/C14H16N2O6/c17-10-5-6-11(18)15(10)9-3-1-2-4-14(21)22-16-12(19)7-8-13(16)20/h5-6H,1-4,7-9H2

InChI 密鑰

VLARLSIGSPVYHX-UHFFFAOYSA-N

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應用

6-马来酰亚胺己酸N-羟基琥珀酰亚胺酯可用于:
  • 通过马来酰亚胺硫醇连接反应合成马来酰亚胺活化碳水化合物,用于含半胱氨酸的多肽和蛋白质的位点特异性糖基化。
  • 含有马来酰亚胺侧链作为抗肿瘤剂的阿霉素葡糖苷酸前药的合成。
  • 将寡核苷酸与底物上的氨基交联以制备DNA微阵列。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Synthesis and antitumor efficacy of a β-glucuronidase-responsive albumin-binding prodrug of doxorubicin.
Legigan T, et al.
Journal of Medicinal Chemistry, 55(9), 4516-4520 (2012)
Microarray fabrication with covalent attachment of DNA using bubble jet technology.
Okamoto T, et al.
Nature Biotechnology, 18(4), 438-438 (2000)
Synthesis of maleimide-activated carbohydrates as chemoselective tags for site-specific glycosylation of peptides and proteins.
Ni J, et al.
Bioconjugate Chemistry, 14(1), 232-238 (2003)
Y Nakano et al.
International archives of allergy and immunology, 120(3), 199-208 (1999-12-11)
We have previously reported that ovalbumin (OVA) coupled with liposome via glutaraldehyde (GA) induced OVA-specific- and IgE-selective unresponsiveness in mice. In this study, OVA-liposome conjugates were made using four different coupling protocols: via GA, N-(6-maleimidocaproyloxy) succinimide (EMCS), disuccinimidyl suberate (DSS)
N J Maeji et al.
Journal of immunological methods, 146(1), 83-90 (1992-01-21)
Recently, the multipin approach for simultaneous multiple peptide synthesis was applied to the analysis of T cell determinants by using a novel cleavage method (Maeji et al., 1990). A diketopiperazine forming linker allowed cleavage of peptides into aqueous buffer which

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