498041

环戊基溴化锌 溶液

0.5 M in THF

• 别名: Bromo(cyclopentyl)zinc, Bromocyclopentylzinc
• 线性分子式: C₅H₉ZnBr
• CAS号: 171860-68-7
• 分子量: 214.42
• MDL號碼: MFCD00671991
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24873166
• NACRES: NA.22

属性

• 濃度: 0.5 M in THF
• 密度: 0.955 g/mL at 25 °C
• 儲存溫度: 2-8°C
• SMILES 字串: Br[Zn]C1CCCC1
• InChI: 1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1
• InChI 密鑰: GOPYCBPMCCJYSN-UHFFFAOYSA-M

说明

應用

Cyclopentylzinc bromide is an organozinc reagent that can be used in:

• The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
• Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
• The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.

法律資訊

Rieke® Metals, Inc. 制造。®Rieke Metals, Inc. 的注册商标。

安全信息

• 象形圖: GHS02,GHS08,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H261,H302,H315,H319,H335,H351
• 防範說明: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• 危險分類: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
• 標靶器官: Respiratory system
• 安全危害: EUH019
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 1.4 °F - closed cup
• 閃點（°C）: -17 °C - closed cup