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化驗
97%
bp
113-114 °C/2 mmHg (lit.)
mp
44-46 °C (lit.)
官能基
sulfoxide
SMILES 字串
Cc1ccc(cc1)S(C)=O
InChI
1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3
InChI 密鑰
FEVALTJSQBFLEU-UHFFFAOYSA-N
一般說明
甲基对甲苯基亚砜(MTSO)是烷基取代的对甲苯基亚砜,是一种路易斯碱。它作为四氯化硅的活化剂,用于氮杂 Diels-Alder 反应。
應用
对甲基苯甲酸亚砜可以用作通过醛与烯丙基三氯硅烷的烯丙基化来制备均烯丙基醇的催化剂。它可以用作氯钼络合物合成中的配体。
注意
低熔点固体
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
其他客户在看
PloS one, 6(11), e26974-e26974 (2011-11-11)
Production of reactive oxygen species represents a fundamental innate defense against microbes in a diversity of host organisms. Oxidative stress, amongst others, converts peptidyl and free methionine to a mixture of methionine-S- (Met-S-SO) and methionine-R-sulfoxides (Met-R-SO). To cope with such
Addition compounds of MoO2Cl2 with chiral sulfoxides. First molecular structures of dioxomolybdenum complexes bearing chiral non-racemic sulfoxide as ligand.
Inorgorganica Chimica Acta, 363(13), 3158-3164 (2010)
A New Approach to Di-and Tetrasubstituted 2,3-Dihydropyridin-4(1H)-ones through Aza-Diels-Alder Reaction Promoted by Silicon Tetrachloride.
Synthesis, 4, 0643-0649 (2009)
Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides.
Tetrahedron Letters, 44(38), 7179-7181 (2003)
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