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Merck
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文件

471933

Sigma-Aldrich

4-碘苯硼酸

≥95.0%

别名:

B-(4-iodophenyl)-boronic acid, p-Iodophenylboronic acid, p-iodo-benzeneboronic acid

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About This Item

线性分子式:
IC6H4B(OH)2
CAS号:
5122-99-6
分子量:
247.83
MDL號碼:
MFCD01319014
分類程式碼代碼:
12352103
PubChem物質ID:
24870773
NACRES:
NA.22

化驗

≥95.0%

mp

326-330 °C (lit.)

SMILES 字串

OB(O)c1ccc(I)cc1

InChI

1S/C6H6BIO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H

InChI 密鑰

PELJYVULHLKXFF-UHFFFAOYSA-N

相关类别

應用

试剂用于
  • 铜介导的无配体好氧氟烷基化
  • 钯催化的好氧氧化交叉偶联反应
  • 用于 Suzuki 偶联反应的可回收磁性纳米离子负载的钯催化剂
  • 使用铜（Cu）催化剂的氧化羟基化
  • 无配体钯催化的 Suzuki-Miyaura 交叉偶联
  • 使用金盐催化剂的同型偶联
  • 钌（Ru）催化的交叉偶联
  • CuI 催化的 Suzuki 偶联反应
  • 钯催化的多米诺骨牌 Heck-Mizoroki/Suzuki-Miyaura 反应
  • 三乙酸锰介导的芳基硼酸向烯烃的自由基加成

试剂用于制备
  • 通过“点击化学”策略合成截短侧耳素衍生物，进行用于研究与核糖体结合和抗菌活性
  • 液晶聚乙炔衍生物

其他說明

含不定量的酸酐

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Samir Yahiaoui et al.
The Journal of organic chemistry, 76(8), 2433-2438 (2011-03-23)
A palladium(II)-catalyzed Heck-Mizoroki/Suzuki-Miyaura domino reaction involving metal coordinating dimethylaminoethyl vinyl ethers and a number of electron-rich and electron-deficient arylboronic acids has been developed. Through variation of the temperature and the concentration of the p-benzoquinone (p-Bq) ligand/reoxidant, conditions for the robust
An efficient and recyclable magnetic-nanoparticle-supported palladium catalyst for the Suzuki coupling reactions of organoboronic acids with alkynyl bromides
X. Zhang, et al.,
Synthesis, 18, 2975-2983 (2011)
Hong Li et al.
Chemical communications (Cambridge, England), 47(27), 7880-7882 (2011-06-11)
The first ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids is reported. Various aliphatic and aromatic aldehydes are transformed to the corresponding arylketones. A total of 31 examples with moderate to excellent yields are presented, together with the results of an
Kazuhiko Tsukagoshi et al.
Journal of chromatography. A, 1123(1), 106-112 (2006-05-24)
Molecular recognition of mono- and disaccharides was performed making use of the interaction between their diol groups and p-iodophenylboronic acid in capillary electrophoresis (CE) with a chemiluminescence (CL) detection system. p-Iodophenylboronic acid acted as an enhancer for luminol-horseradish peroxidase-hydrogen peroxide
Disubstituted Liquid Crystalline Polyacetylene Derivatives That Exhibit Linearly Polarized Blue and Green Emissions
San Jose, B. A.; et al.
Macromolecules, 44, 6288-6302 (2011)
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