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化驗
97%
折射率
n20/D 1.407 (lit.)
bp
138 °C (lit.)
密度
1.039 g/mL at 25 °C (lit.)
SMILES 字串
C[Si](C)(Cl)O[Si](C)(C)Cl
InChI
1S/C4H12Cl2OSi2/c1-8(2,5)7-9(3,4)6/h1-4H3
InChI 密鑰
DMEXFOUCEOWRGD-UHFFFAOYSA-N
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應用
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane can be used to prepare:
- A Silicon-based fluorene polymer by reacting with a dibromofluorene derived Grignard reagent.
- ansa-Metallocene compound i.e, ansa-[TiCl2{η5:η5-(C5H4SiMe2)2O}].
- Silaanthracenophanes.
訊號詞
Danger
危險聲明
危險分類
Flam. Liq. 2 - Skin Corr. 1B
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
59.0 °F - closed cup
閃點(°C)
15 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Synthesis and crystal structures of μ-1, 3-bis (η5-tetramethylcyclopentadienyl)-1, 1, 3, 3-tetramethyldisiloxane)[ η2-bis (trimethylsilyl) ethyne] titanium (II) and a doubly tucked-in product of its thermolysis
Journal of Organometallic Chemistry, 658(1-2), 235-241 (2002)
Carbon-Silicon coupling between fluorenyl Grignard reagents and dichlorosilanes for synthesis of novel copolymers and chemical properties of the copolymers
Applied Organometallic Chemistry, 17(11), 840-842 (2003)
Synthesis and Structures of New Silaanthracenophanes
Bulletin of the Korean Chemical Society,, 33(1), 255-260 (2012)
Chemical science, 10(42), 9841-9852 (2020-02-06)
Ring-opening polymerisation (ROP) of strained [1]- and [2]metallocenophanes and related species is well-established, and the monomer ring-strain is manifest in a substantial tilting of the cyclopentadienyl ligands, giving α angles of ∼14-32°. Surprisingly, tetracarba[4]nickelocenophane [Ni(η5-C5H4)2(CH2)4] (2) undergoes ROP (pyridine, 20
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