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等級
anhydrous
化驗
≥99.999% trace metals basis
形狀
powder
反應適用性
reagent type: catalyst
core: indium
雜質
<100 ppm H2O
密度
3.46 g/mL at 25 °C (lit.)
SMILES 字串
Cl[In](Cl)Cl
InChI
1S/3ClH.In/h3*1H;/q;;;+3/p-3
InChI 密鑰
PSCMQHVBLHHWTO-UHFFFAOYSA-K
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一般說明
InCl3 是一种高效的水稳定性路易斯酸催化剂,用于多种有机转化。它具有中等毒性,对大多数含氧和含氮官能团表现出高耐受性。由于其光电特性,它也被用于制备多种半导体材料。
應用
氯化铟(III)可以用作催化剂来合成:
- 吲哚吲哚啉,通过吲哚的自加成作用。
- 乙烯基吲哚,通过未官能化的吲哚和乙烯基叠氮化物。
- 各种环加合物,通过烯烃缩醛与异戊二烯和环戊二烯反应生成。
- N-甲苯磺酰胺,通过醛与对甲苯磺酰胺的缩合反应生成。
訊號詞
Danger
危險聲明
危險分類
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation
標靶器官
Lungs
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
其他客户在看
Mechanisms of synthesis reaction of pure anhydrous indium(III) chloride
Wieslaw Gawel and Tomasz Kloc and Igor Mucha
Inorganica chimica acta, 495, 118991-118991 (2019)
Naveen Mulakayala et al.
Bioorganic & medicinal chemistry letters, 22(15), 5063-5066 (2012-07-04)
A convenient and practical methodology for the synthesis of 2-aryl quinazolin-4(3H)-ones by the condensation of o-aminobenzamides with aromatic aldehydes under mild conditions using catalytic InCl(3) with good yields and high selectivities. This method has been extended for the synthesis of
Masateru Ono et al.
Journal of natural products, 73(11), 1846-1852 (2010-10-14)
Treatment of the crude ether-insoluble resin glycoside (convolvulin) from seeds of Pharbitis nil (Pharbitis Semen), called pharbitin, with indium(III) chloride in methanol provided seven oligoglycosides of hydroxy fatty acid methyl esters partially acylated by 2-methyl-3-hydroxybutyric (nilic) and 2S-methylbutyric acids. Their
Enrique Font-Sanchis et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 2470-2473 (2009-03-26)
A simple method for the preparation of triorganoindium reagents under mild conditions based in indium-silicon exchange is described.
Christine Rangger et al.
International journal of nanomedicine, 7, 5889-5900 (2012-12-12)
Liposomes have been proposed to be a means of selectively targeting cancer sites for diagnostic and therapeutic applications. The focus of this work was the evaluation of radiolabeled PEGylated liposomes derivatized with varying amounts of a cyclic arginyl-glycyl-aspartic acid (RGD)
商品
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
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