所有图片(3)
About This Item
线性分子式:
(CH3)3SiONa
CAS号:
分子量:
112.18
Beilstein:
3912148
EC號碼:
MDL號碼:
分類程式碼代碼:
12352000
PubChem物質ID:
NACRES:
NA.22
推荐产品
化驗
95%
形狀
powder
mp
230 °C ((lit.))
230 °C (dec.) (lit.)
SMILES 字串
[[Na+].C[Si](C)(C)[O-]]
[Na+].C[Si](C)(C)[O-]
InChI
[1S/C3H9OSi.Na/c1-5(2,3)4;/h1-3H3;/q-1;+1]
1S/C3H9OSi.Na/c1-5(2,3)4;/h1-3H3;/q-1;+1
InChI 密鑰
[HSNUIYJWTSJUMS-UHFFFAOYSA-N]
HSNUIYJWTSJUMS-UHFFFAOYSA-N
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一般說明
三甲基硅氧基钠是一种性能强大的多功能试剂，用于酯转化生成羧酸和腈水解生成伯酰胺。它可作为起始原料用于通过盐复分解合成金属硅醇盐，也可作为催化剂用于硅烷醇和含氢硅烷的硅烷化反应。
應用
三甲基硅烷醇钠用作以下反应中的催化剂：
- 硅酸铑配合物的合成。
- 甲基苯基硅烷与叔丁基二甲基硅烷醇的硅烷化反应合成三硅氧烷。
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
230.0 °F - closed cup
閃點（°C）
110 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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We developed a new assay method for fluoride anion (F(-)) a specific metabolite of sarin. Trimethyifluorosilane (TMFS) was derivatized from F(-) with trimethylsilanol, and TMFS was detected with a GC-flame ionization detector (FID) and capillary column system. The linear range
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The assignment of the SiOH group vibrations of trimethylsilanol, which is still controversial, is proposed. This assignment is based on theoretical B3LYP force field scaled using the constants of the (CH3)3Si group optimized to fit experimental vibrational frequencies of (CH3)3SiF
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A methodology is presented for the determination of dihydroxy fatty acids preserved in the 'bound' phase of organic residues preserved in archaeological potsherds. The method comprises saponification, esterification, silica gel column chromatographic fractionation, and analysis by gas chromatography/mass spectrometry. The
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