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品質等級
化驗
99%
bp
264 °C (lit.)
mp
164-166 °C (lit.)
SMILES 字串
Cc1c(C)c(C)c(C)c(C)c1C
InChI
1S/C12H18/c1-7-8(2)10(4)12(6)11(5)9(7)3/h1-6H3
InChI 密鑰
YUWFEBAXEOLKSG-UHFFFAOYSA-N
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一般說明
Hexamethylbenzene, also known as Mellitene, is an arene ligand that is commonly used as a precursor in the synthesis of organometallic complex.
應用
- 姜黄素和双去甲氧基姜黄素代谢产物的Ru(II)-芳烃络合物：研究Ru(II)-芳烃络合物与姜黄素代谢物的结构和反应性，为涉及六甲基苯衍生物的药物开发和合成途径的潜在应用提供启示（Dyson et al., 2024）。
- 大气中OH自由基降解聚甲基取代苯的理论研究：对包括六甲基苯在内的多甲基取代苯与OH自由基的大气反应进行全面的计算分析，以了解其环境影响（Zhao et al., 2024）。
- 重新审核五棱锥形C(6)H(6)(2+)和C(6)(CH(3))(6)(2+)指示键：探索了指示形式的六甲基苯的独特键和结构特征，为其在各种电子条件下的化学行为提供了启示（Torres et al., 2023）。
- 萘二亚胺功能化半夹层Ru（II）络合物作为线粒体靶向抗癌和抗转移药物的研究：讨论了六甲基苯结构Ru（II）络合物的合成和生物学评价，旨在开发新的治疗剂（Yang et al., 2023）。
- 不同反应条件下有机化合物对镍合金碳侵蚀的比较研究：研究了包括六甲基苯在内的有机化合物对工业应用相关镍合金的磨损和腐蚀的影响（Volodin et al., 2022）。
Hexamethylbenzene is used as a reagent during the synthesis of ketodiepoxides via hydroxylation reactions.
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
其他客户在看
Yaw Kai Yan et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 11(4), 483-488 (2006-04-11)
Ruthenium(II) arene anticancer complexes [(eta6-arene)Ru(en)Cl]PF6 (arene is hexamethylbenzene, p-cymene, indan; en is ethylenediamine) can catalyse regioselective reduction of NAD+ by formate in water to form 1,4-NADH, at pD 7.2, 37 degrees C, and in the presence of air. The catalytic
I García Cuesta et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 7(12), 2503-2507 (2006-10-24)
High-level quantum-chemical methods show that the binding in the inclusion complex of hexamethylbenzene (HMB) in 6-cycloparaphenilacetylene (6-CPPA) cannot be explained only in terms of electrostatic interactions-caused by the polarization associated to curved pi-conjugated systems-and the inclusion of dispersion forces is
H J Jakobsen et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 156(1), 152-154 (2002-06-26)
The design of a broadband 4-mm magic-angle spinning (MAS) X-(1)H/(19)F double resonance probe for cross-polarization (CP)/MAS NMR studies at 21.15 T ((1)H at 900 MHz) is described. The high-frequency (1)H/(19)F channel employs a new and efficient transmission line tuning design.
Kohji Yamamoto et al.
Physical chemistry chemical physics : PCCP, 7(9), 1945-1952 (2005-05-07)
We have measured the frequency dependent extinction coefficients and refractive indices of electron donor-acceptor (EDA) complexes consisting of hexamethylbenzene (HMB; electron donor) and tetracyanoethylene (TCNE; electron acceptor) in the low-frequency region by terahertz time-domain spectroscopy (THz-TDS). A mixture of the
Xiang Ma et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 211(2), 134-142 (2011-06-15)
We report on an analysis of a well known three-pulse sequence for generating and detecting spin I=1 quadrupolar order when various pulse errors are taken into account. In the situation of a single quadrupolar frequency, such as the case found
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