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About This Item
线性分子式:
(CH3)2C=CHCH2CH2C(CH3)=CHCH2Cl
CAS号:
分子量:
172.69
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級
化驗
95%
形狀
liquid
折射率
n20/D 1.4808 (lit.)
bp
102-104 °C/12 mmHg (lit.)
密度
0.931 g/mL at 25 °C (lit.)
官能基
alkyl halide
chloro
SMILES 字串
C\C(C)=C\CC\C(C)=C\CCl
InChI
1S/C10H17Cl/c1-9(2)5-4-6-10(3)7-8-11/h5,7H,4,6,8H2,1-3H3/b10-7+
InChI 密鑰
WLAUCMCTKPXDIY-JXMROGBWSA-N
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一般說明
Geranyl chloride undergoes palladium-catalyzed cross-coupling reaction with aryl and alkenylgold(I) phosphanes to afford the α-substitution product.
應用
Geranyl chloride was used as starting reagent in the synthesis of:
- C25 compound moenocinol
- 2-methyl-6-geranylphenol
- manoalide and seco-manoalide analogs
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
194.0 °F - closed cup
閃點（°C）
90 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Preparation and oxidative polymerization of 2-methyl-6-geranylphenol.
Hyun SH, et al.
Polymer Bull., 18(4), 283-286 (1987)
Toward elucidation of the inhibition mechanism of phospholipase A< sub> 2</sub> by manoalide: selectively modified amino acid residues by manoalide analogues.
Katsumura S, et al.
Bioorganic & Medicinal Chemistry Letters, 2(10), 1267-1268 (1992)
A synthesis of moenocinol from isoprenoid precursors.
Bottger D and Welzel P.
Tetrahedron Letters, 24(47), 5201-5204 (1983)
Palladium-catalyzed cross-coupling reactions of organogold(I) phosphanes with allylic electrophiles.
Miguel Peña-López et al.
Organic & biomolecular chemistry, 10(8), 1686-1694 (2012-01-24)
Aryl and alkenylgold(I) phosphanes react regioselectively with allylic electrophiles such as cinnamyl and geranyl halides (bromide, chloride and acetates) under palladium catalysis in THF at 80 °C to afford the α-substitution product with moderate to high yields. When the reaction
Lisa Becks et al.
BMC cancer, 10, 540-540 (2010-10-12)
Activation of nuclear factor erythroid 2-related factor (Nrf2), which belongs to the basic leucine zipper transcription factor family, is a strategy for cancer chemopreventive phytochemicals. It is an important regulator of genes induced by oxidative stress, such as glutathione S-transferases
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