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Merck

280895

Sigma-Aldrich

4-溴重氮苯四氟化硼酸盐

96%

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About This Item

线性分子式:
BrC6H4N2BF4
CAS号:
分子量:
270.82
Beilstein:
3791621
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

96%

mp

135-140 °C (dec.) (lit.)

官能基

bromo

儲存溫度

2-8°C

SMILES 字串

F[B-](F)(F)F.Brc1ccc(cc1)[N+]#N

InChI

1S/C6H4BrN2.BF4/c7-5-1-3-6(9-8)4-2-5;2-1(3,4)5/h1-4H;/q+1;-1

InChI 密鑰

FXTCQUCYDJZGGU-UHFFFAOYSA-N

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一般說明

已经研究了4-溴苯重氮四氟硼酸盐的电化学还原反应,用于碳毡的衍生化(改性碳表面,无论是玻璃碳还是碳毡)

應用

4-溴苯基重氮四氟硼酸盐被用于制备:
  • 表面改性的Au(111)电极
  • 1-(4′-溴苯基)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟代-1-烯

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Bo Cui et al.
Langmuir : the ACS journal of surfaces and colloids, 29(9), 2955-2960 (2013-02-16)
Surface modifications of a Au(111) electrode with 4-bromobenzenediazonium tetrafluoroborate (BBD) in acetonitrile (ACN) and 0.1 M HClO4 have been characterized by scanning tunneling microscopy (STM). In ACN, STM results reveal the formation of disordered thin organic films. The involvement of
Electrochemical attachment of organic groups to carbon felt surfaces.
Coulon E, et al.
Langmuir, 17(22), 7102-7106 (2001)
Efficient access to perfluoroalkylated aryl compounds by Heck reaction.
Darses S, et al.
European Journal of Organic Chemistry, 2001(6), 1121-1128 (2001)
Tomonari Shiraishi et al.
Nanoscale, 9(43), 16900-16907 (2017-10-28)
Single-walled carbon nanotubes (SWNTs) with local chemical modification have been recognized as a novel near infrared (NIR) photoluminescent nanomaterial due to the emergence of a new red-shifted photoluminescence (PL) with enhanced quantum yields. As a characteristic feature of the locally
Nicolai F Hartmann et al.
Nanoscale, 7(48), 20521-20530 (2015-11-21)
Covalent dopants in semiconducting single wall carbon nanotubes (SWCNTs) are becoming important as routes for introducing new photoluminescent emitting states with potential for enhanced quantum yields, new functionality, and as species capable of near-IR room-temperature single photon emission. The origin

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