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Merck

276316

Sigma-Aldrich

1-溴-3,5-二甲苯

97%

别名:

5-溴-m-二甲苯

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About This Item

线性分子式:
(CH3)2C6H3Br
CAS号:
分子量:
185.06
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

liquid

折射率

n20/D 1.549 (lit.)

bp

202-204 °C (lit.)

密度

1.362 g/mL at 25 °C (lit.)

官能基

bromo

SMILES 字串

Cc1cc(C)cc(Br)c1

InChI

1S/C8H9Br/c1-6-3-7(2)5-8(9)4-6/h3-5H,1-2H3

InChI 密鑰

LMFRTSBQRLSJHC-UHFFFAOYSA-N

一般說明

钯催化的1-溴-3,5-二甲基苯和甲酚与氢氧化钾的碳氧偶联可生成甲苯基-3,5-二甲苯基醚

應用

1-溴-3,5-二甲基苯已用于合成取代的2,2′-(二苯基磷烷基甲基)-1,1′-联萘衍生物

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

188.6 °F - closed cup

閃點(°C)

87 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Highly Selective Catalyst Systems for the Hydroformylation of Internal Olefins to Linear Aldehydes This work was supported by Oxeno Olefinchemie GmbH and the State of Mecklenburg-West Pommerania. Dr. C. Fischer and Mrs. S. Buchholz are thanked for their excellent technical support.
Holger Klein et al.
Angewandte Chemie (International ed. in English), 40(18), 3408-3411 (2001-10-10)
Vittoria M Blasucci et al.
The journal of physical chemistry. A, 114(11), 3932-3938 (2010-03-20)
Tunable solvent systems couple homogeneous catalytic reactions to heterogeneous separations, thereby combining multiple unit operations into a single step and subsequently reducing waste generation and improving process economics. In addition, tunable solvents can require less energy than traditional separations, such
Tapan K Pal et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(52), 19064-19070 (2015-11-21)
By using a bent tetracarboxylic acid ligand that incorporates a pendent-NH2 functional group, a 3D Zn(II)-framework (1) based on Zn2 (CO2)4 secondary building units and Zn12 (CO2)24 supramolecular building blocks has been synthesized. Framework 1 is thermally less stable, which

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