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Merck

B56501

Sigma-Aldrich

4-溴苯甲醚

≥99.0%

别名:

1-溴-4-甲氧基苯

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About This Item

线性分子式:
BrC6H4OCH3
CAS号:
分子量:
187.03
Beilstein:
1237590
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥99.0%

形狀

liquid

折射率

n20/D 1.564 (lit.)

bp

223 °C (lit.)

mp

9-10 °C (lit.)

密度

1.494 g/mL at 25 °C (lit.)

SMILES 字串

COc1ccc(Br)cc1

InChI

1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3

InChI 密鑰

QJPJQTDYNZXKQF-UHFFFAOYSA-N

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一般說明

4-溴苯甲醚一种实用的溴化试剂。它是在HOBr与苯甲醚之间的反应中形成的反应产物。已有研究报道了由钳形钯复合物催化的4-溴苯甲醚与苯硼酸的Suzuki偶联反应。据报道,在室温离子液体中,4-溴苯甲醚与丙烯酸乙酯发生Heck反应,形成4-甲氧基肉桂酸。

應用

4-溴苯甲醚被用于合成芳基1,3-二酮。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Skin Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

201.2 °F

閃點(°C)

94 °C

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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商品

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

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