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About This Item
线性分子式:
(CH3)3Al
CAS号:
分子量:
72.09
Beilstein:
3587197
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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一般說明
Trimethylaluminum is a Lewis acid having wide applications in organic synthesis. It is employed in organic reactions like cross-coupling reaction, methylenation, carboalumination, cyclopropanation, and rearrangement reactions. Tebbe Reagent (methylenation agent) can be prepared in situ by reacting trimethylaluminum with dichlorobis(cyclopentadienyl)titanium.
應用
与 4-溴-2,6-二叔丁基苯酚（货号394378）一起用于通过环氧化物的选择性重排制备各种羰基化合物。
訊號詞
Danger
危險分類
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Central nervous system
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
-0.4 °F - closed cup
閃點（°C）
-18 °C - closed cup
Tetrahedron, 47, 6983-6983 (1991)
Tetrahedron Letters, 30, 5607-5607 (1989)
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