推荐产品
等級
reagent grade
反應適用性
reagent type: reductant
bp
116-118 °C/1 mmHg (lit.)
密度
0.798 g/mL at 25 °C (lit.)
SMILES 字串
[H][Al](CC(C)C)CC(C)C
InChI
1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
InChI 密鑰
AZWXAPCAJCYGIA-UHFFFAOYSA-N
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一般說明
二异丁基氢化铝通常用作有机合成中的还原剂。
應用
二异丁基氢化铝可用于以下实验方案：
- 作为醛类Tishchenko反应的促进剂。
- 将1,2-和1,3-二醇的亚苄基缩醛转化为二醇的相应单苄基醚。
- 以（S）-脯氨酸为原料制备一种新型手性还原剂，用于前手性酮的不对称还原。
包裝
法律資訊
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
nwg
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Tishchenko reactions of aldehydes promoted by diisobutylaluminum hydride and its application to the macrocyclic lactone formation.
Hon YS, et al.
Tetrahedron, 63(46), 11325-11340 (2007)
A facile cleavage of benzylidene acetals with diisobutylaluminum hydride.
Takano S, et al.
Chemistry Letters (Jpn), 12(10), 1593-1596 (1983)
Asymmetric reduction of prochiral keto esters with a chiral reducing agent prepared from tin (II) chloride, chiral diamine, and diisobutylaluminum hydride.
Mukaiyama T, et al.
Chemistry Letters (Jpn), 14(6), 813-816 (1985)
Daisuke Ando et al.
Journal of agricultural and food chemistry, 66(39), 10154-10162 (2018-09-13)
The metabolic fate of a new fungicide, mandestrobin, labeled with 14C at the phenoxy or benzyl ring was examined in wheat after a single spray application at 300 g/ha. Mandestrobin penetrated into foliage over time, with both radiolabels showing similar
Reaction of diisobutylaluminum hydride with selected organic compounds containing representative functional groups
Yoon N M
The Journal of Organic Chemistry, 50(14), 2443-2450 (1985)
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