跳转至内容
Merck
所有图片(2)

文件

254037

Sigma-Aldrich

氯化三苯基磷金(I)

≥99.9% trace metals basis

别名:

(Ph3P)AuCl, 三苯基膦氯化金(I)

登录查看公司和协议定价
所有图片(2)

About This Item

线性分子式:
[(C6H5)3P]AuCl
CAS号:
14243-64-2
分子量:
494.71
EC號碼:
238-117-6
MDL號碼:
MFCD00009588
分類程式碼代碼:
12161600
PubChem物質ID:
24855348
NACRES:
NA.22

化驗

≥99.9% trace metals basis

形狀

solid

反應適用性

core: gold
reagent type: catalyst

SMILES 字串

Cl[Au].c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI

1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1

InChI 密鑰

IFPWCRBNZXUWGC-UHFFFAOYSA-M

相关类别

應用

金催化剂— 21世纪 ′淘金热′
在室温下通过5-exo-digonal 途径将O-炔丙基氨基甲酸酯环化为亚烷基新恶唑烷酮（alkylideneoxazolidinones ）的催化剂。在室温下也催化含环烯烃的烯炔的环化异构化，生成高度稠合的多环二烯。
该试剂可与助催化卤化物提取剂一起使用以激活 π-系统通过杂原子和碳亲核试剂进行加成。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ （Lot或Batch）字后找到。

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Ming Zhang et al.
Molecules (Basel, Switzerland), 17(3), 2812-2822 (2012-03-08)
An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh(3))AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free conditions with low catalyst loading in good
Elena Barreiro et al.
Journal of inorganic biochemistry, 102(2), 184-192 (2007-09-18)
The reaction of triphenylphosphinegold(I) chloride in ethanol in a 1:1 molar ratio with the 3-(aryl)-2-sulfanylpropenoic acids H(2)xspa [x: p=3-phenyl-, Clp=3-(2-chlorophenyl)-, -o-mp=3-(2-methoxyphenyl)-, -p-mp=3-(4-methoxyphenyl)-, -o-hp=3-(2-hydroxyphenyl)-, -p-hp=3-(4-hydroxyphenyl)-, diBr-o-hp=3-(3,5-dibromo-2-hydroxyphenyl)-, f=3-(2-furyl)-, t=3-(2-thienyl)-, -o-py=3-(2-pyridyl)-; spa=2-sulfanylpropenoato] gave compounds of the type [Au(PPh(3))(Hxspa)], which were isolated and characterized
Sang Ick Lee et al.
The Journal of organic chemistry, 71(25), 9366-9372 (2006-12-02)
Gold(I)-catalyzed cyclization of enynes containing an olefinic cycle has been studied. The introduction of an olefinic ring instead of a terminal alkene in enynes dramatically increased the yield of the reaction. Enynes having an olefinic cycle were prepared by a
Leseurre, L. et al.
Organic Letters, 9 (2007)
Synlett, 3309-3309 (2006)
查看所有相关文献

商品

Fluorinating Reagents

The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinating agents that can operate safely and efficiently.

Fluorinating Reagents

The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinating agents that can operate safely and efficiently.

Gold Catalyst

We are proud to offer a treasure-trove of gold precatalysts and silver salts, as well as an extensive portfolio of unsaturated building blocks to accelerate your research success in this exciting field.

Gold Catalyst

We are proud to offer a treasure-trove of gold precatalysts and silver salts, as well as an extensive portfolio of unsaturated building blocks to accelerate your research success in this exciting field.

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门