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About This Item
线性分子式:
CH3CH2AlCl2
CAS号:
分子量:
126.95
Beilstein:
4123357
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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應用
Ethylaluminum dichloride is a strong Lewis acid and a proton scavenger that can be used:
- To catalyze polymerization of isobutylene.
- To facilitate Diels-Alder reaction of α,β-unsaturated esters.
- To carry out Pinacol reduction rearrangements.
- To promote Schmidt rearrangement of diketoazides in the synthesis of indolizidines and pyrroloazepinediones.
訊號詞
Danger
危險分類
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3 - Water-react 2
標靶器官
Central nervous system, Nervous system
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
-9.4 °F - closed cup
閃點（°C）
-23 °C - closed cup
Concise access to indolizidine and pyrroloazepine skeleta via intramolecular Schmidt reactions of azido 1, 3-diketones.
Lertpibulpanya D and Marsden S P
Organic & Biomolecular Chemistry, 4(18), 3498-3504 (2006)
Cyclorearrangement and cycloolefination of keto-bis-sulfones. A sulfone analog of a pinacol reduction-rearrangement.
Trost B M, et al.
Journal of the American Chemical Society, 114(13), 5432-5434 (1992)
Kinetic and Mechanistic Studies of the Polymerization of Isobutylene Catalyzed by EtAlCl2/Bis (2-chloroethyl) Ether Complex in Hexanes.
Banerjee S, et al.
Macromolecules, 48(16), 5474-5480 (2015)
Ethylaluminum Dichloride.
Snider B B.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Ethylaluminum Dichloride.
Snider B B.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
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