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化驗
99%
形狀
solid
bp
237-238 °C (lit.)
mp
33-35 °C (lit.)
SMILES 字串
C1C\C=C\CC\C=C\CC\C=C\1
InChI
1S/C12H18/c1-2-4-6-8-10-12-11-9-7-5-3-1/h1-2,7-10H,3-6,11-12H2/b2-1+,9-7+,10-8+
InChI 密鑰
ZOLLIQAKMYWTBR-FFWAUJBHSA-N
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一般說明
trans,trans,trans-1,5,9-Cyclododecatriene (ttt-cdt) acts as ligand and forms rare copper complexes. Photorearrangements of CuCl complexes of ttt-cdt has been investigated.
應用
trans,trans,trans-1,5,9-Cyclododecatriene has been used in the construction of building block for the synthesis of potent antitumor annonaceous acetogenin (+)-parviflorin.
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類(WGK)
WGK 3
閃點(°F)
163.4 °F - closed cup
閃點(°C)
73 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Highly efficient synthesis of the potent antitumor annonaceous acetogenin (+)-parviflorin.
Journal of the American Chemical Society, 118(7), 1801-1802 (1996)
Dalton transactions (Cambridge, England : 2003), (12)(12), 2085-2087 (2009-03-11)
Two rare copper complexes, a tri-alkene adduct [Cu(ttt-cdt)(FSbF(5))] and a non-classical carbon monoxide complex [Cu(ttt-cdt)(CO)][SbF(6)] with a high CO stretching frequency ([small nu, Greek, macron](CO) = 2160 cm(-1)), have been isolated using trans,trans,trans-1,5,9-cyclododecatriene (ttt-cdt) ligand.
Photorearrangements of CuCl complexes of 1, 5, 9-cyclododecatrienes: wavelength dependence.
Organometallics, 6(5), 1126-1129 (1987)
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