227226

1-三甲基硅氧基-1,3-丁二烯

98%

• 别名: (1,3-Butadien-1-yloxy)trimethylsilane, (1,3-Butadienyloxy)trimethylsilane, (Butadienyloxy)trimethylsilane, 1-(Trimethylsiloxy)butadiene, 1-[(Trimethylsilyl)oxy]-1,3-butadiene, 1-[(Trimethylsilyl)oxy]butadiene
• 线性分子式: (CH₃)₃SiOCH=CHCH=CH₂
• CAS号: 6651-43-0
• 分子量: 142.27
• Beilstein: 1902024
• MDL號碼: MFCD00009647
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24853620
• NACRES: NA.22

属性

• 化驗: 98%
• 形狀: liquid
• 折射率: n20/D 1.448 (lit.)
• bp: 131 °C (lit.)
• 密度: 0.811 g/mL at 25 °C (lit.)
• 儲存溫度: 2-8°C
• SMILES 字串: C[Si](C)(C)O\C=C\C=C
• InChI: 1S/C7H14OSi/c1-5-6-7-8-9(2,3)4/h5-7H,1H2,2-4H3/b7-6+
• InChI 密鑰: UQGOYQLRRBTVFM-VOTSOKGWSA-N

说明

一般說明

Mechanism of Diels-Alder reaction between 1-(trimethylsiloxy)-1,3-butadiene and 4,6-dinitrobenzofuroxan has been studied using state-of-the-art computational methods.

應用

1-(Trimethylsiloxy)-1,3-butadiene is commonly employed as diene in the Diels-Alder reaction.

安全信息

• 象形圖: GHS02,GHS07
• 訊號詞: Warning
• 危險聲明: H226,H315,H319,H335
• 防範說明: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 77.0 °F - closed cup
• 閃點（°C）: 25 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter