218847

三氟化硼二甲醚

• 别名: (Dimethyl ether)trifluoroboron
• 线性分子式: BF₃ · O(CH₃)₂
• CAS号: 353-42-4
• 分子量: 113.87
• Beilstein: 3613739
• EC號碼: 206-532-1
• MDL號碼: MFCD00013192
• 分類程式碼代碼: 12352106
• PubChem物質ID: 24853093
• NACRES: NA.22

属性

• 形狀: liquid
• 品質等級: 100
• 自燃溫度: 455 °F
• expl. lim.: 21.6 %
• 反應適用性: core: boron; reagent type: Lewis acid; reagent type: catalyst
• 折射率: n20/D 1.308 (lit.)
• bp: 126-127 °C (lit.)
• mp: −15 °C (lit.)
• 密度: 1.239 g/mL at 25 °C (lit.)
• 官能基: ether
• SMILES 字串: C[O+](C)[B-](F)(F)F
• InChI: 1S/C2H6BF3O/c1-7(2)3(4,5)6/h1-2H3
• InChI 密鑰: FOWZWMGLMYVYDH-UHFFFAOYSA-N

说明

應用

Reactant or reagent involved in:

• Deconvoluting the chemical reaction kinetics of platinum-silver ligand exchange
• Synthesis of neurogenic ganglioside LLG-3 from starfish via glycosylation reactions
• Synthesis of peloruside via lactonization and relay ring-closing metathesis cyclization
• FRET for monitoring Pd-catalyzed nucleophilic allylic substitution reactions
• Single molecuel imaging of fluorophore-tagged palldium(II) complexes
• β-elimination and rearrangement reactions for synthesis of exocyclic vinyl ethers

安全信息

• 象形圖: GHS02,GHS08,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H260,H302 + H332,H314,H335,H373
• 防範說明: P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• 危險分類: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 3 - Water-react 1
• 標靶器官: Kidney, Respiratory system
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 143.6 °F - closed cup
• 閃點（°C）: 62 °C - closed cup
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter