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Merck
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215554

Sigma-Aldrich

碘化亚铜

99.999% trace metals basis

别名:

碘化亚铜

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About This Item

经验公式（希尔记法）:
CuI
CAS号:
7681-65-4
分子量:
190.45
EC號碼:
231-674-6
MDL號碼:
MFCD00010978
分類程式碼代碼:
12352302
eCl@ss:
38150105
PubChem物質ID:
24852902
NACRES:
NA.23

蒸汽壓力

10 mmHg ( 656 °C)

化驗

99.999% trace metals basis

形狀

powder and chunks

雜質

≤15.0 ppm Trace Metal Analysis

bp

1290 °C/1 atm (decomp)(lit.)

mp

605 °C (lit.)

溶解度

dilute aqueous acid: insoluble(lit.)

密度

5.62 g/mL at 25 °C (lit.)

應用

battery manufacturing

SMILES 字串

[Cu+].[I-]

InChI

1S/Cu.HI/h;1H/q+1;/p-1

InChI 密鑰

LSXDOTMGLUJQCM-UHFFFAOYSA-M

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應用

碘化亚铜可作为催化剂用于：
  • 在温和、无配体条件下，通过偶联芳香重氮类化合物，芳基化吡唑及衍生物。
  • 通过二溴烯烃与杂亲核试剂的选择性交叉偶联反应，形成各种合成砌块，例如1-溴烯酰胺、炔酰胺、烯酮N,N-缩醛、1-溴烯醇醚、炔醇醚、烯酮O,O-缩醛、乙烯基膦酸酯。
  • 环硅丙烷和羰基化合物的立体特异性和区域选择性反应。
也可用作起始原料，用于二苯基吡啶基膦衍生物(PyrPHOS)-碘化亚铜配合物的制备，用于OLED。

特點和優勢

  • 低毒
  • 反应条件温和
  • 高纯度保证重现性，防止污染物造成的共催化。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral

標靶器官

Thyroid

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Synlett, 1836-1836 (2007)
Synlett, 1917-1917 (2007)
Shuyan Gao et al.
Journal of hazardous materials, 211-212, 55-61 (2012-02-07)
An environment friendly bioinspired strategy for synthesizing hierarchically micro/nano-structured CuI tetrahedron has been developed by combining the stabilization and the reduction performances of l-tryptophan together. A possible growth mechanism of such hierarchical tetrahedron is tentatively proposed. Remarkably, such CuI tetrahedron
Yingguang Zhu et al.
Organic letters, 15(8), 1942-1945 (2013-04-03)
A mild and highly efficient Cu(I)-catalyzed oxidative coupling of anilines is described. Various primary and secondary anilines can be efficiently coupled under mild conditions to the corresponding azo compounds and hydrazines in high yields. This method provides a direct and
Taehwan Jun et al.
Advanced materials (Deerfield Beach, Fla.), 30(43), e1804547-e1804547 (2018-09-15)
Halide perovskites, including CsPbX3 (X = Cl, Br, I), have gained much attention in the field of optoelectronics. However, the toxicity of Pb and the low photoluminescence quantum yield (PLQY) of these perovskites hamper their use. In this work, new
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