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Merck

202231

Sigma-Aldrich

乙酰丙酮铬

97%

别名:

2,4-戊二酮铬, Cr(acac)3

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About This Item

线性分子式:
Cr(C5H7O2)3
CAS号:
分子量:
349.32
Beilstein:
4148971
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

97%

形狀

solid

反應適用性

core: chromium

bp

340 °C (lit.)

mp

210 °C (lit.)

SMILES 字串

CC(=O)\C=C(\C)O[Cr](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Cr/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI 密鑰

JWORPXLMBPOPPU-LNTINUHCSA-K

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應用

  • 氧化还原催化:讨论乙酰丙酮铬(III)的配体场激活氧化还原活性,重点介绍其在加氢催化中的应用(Vinum et al., 2020)。
  • 超临界CO2中的扩散行为:一项研究考察了乙酰丙酮铬(III)在超临界CO2中的扩散行为,有助于超临界流体在材料加工中的应用(Cordeiro et al., 2016)。

分析報告

用于对在其存在下形成的固体聚氨酯进行表面改性。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

>392.0 °F

閃點(°C)

> 200 °C

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Yi Wang et al.
Journal of medicinal chemistry, 56(23), 9601-9611 (2013-11-28)
Current precious-metal-containing anticancer agents are mostly chelated with N-containing ligands and function by interacting with DNA. In the present study, Pd(acac)2, a Pd(II) complex containing four O-donor ligands, has been evaluated as an active anticancer agent. Pd(acac)2 showed no interaction
Gong-Jun Chen et al.
Dalton transactions (Cambridge, England : 2003), 39(44), 10637-10643 (2010-10-06)
Two Eu(III) complexes, [Eu(acac)(3)(dpq)] (1) and [Eu(acac)(3)(dppz)] CH(3)OH (2) {viz. acetylacetonate (acac), dipyrido[3,2-d:20,30-f]quinoxaline (dpq), dipyrido[3,2-a:20,30-c] phenazine (dppz)}, have been synthesized and their DNA binding, photo-induced DNA cleavage activity and cell cytotoxicity are studied. The complexes display significant binding propensity to
The direct writing of plasmonic gold nanostructures by electron-beam-induced deposition.
Katja Höflich et al.
Advanced materials (Deerfield Beach, Fla.), 23(22-23), 2657-2661 (2011-05-04)
Channa R De Silva et al.
Journal of the American Chemical Society, 131(18), 6336-6337 (2009-04-17)
Nearly monodisperse lanthanide-doped magnetite nanoparticles were obtained by thermally decomposing a mixture of Fe(acac)(3) and Ln(acac)(3) (acac = acetylacetonate; Ln = Sm, Eu, Gd) in the presence of passivating surfactants. Magnetic studies revealed room-temperature ferromagnetic behaviors of these doped nanoparticles
Zhan'ao Tan et al.
Physical chemistry chemical physics : PCCP, 14(42), 14589-14595 (2012-09-28)
A solution-processed vanadium oxide (s-VO(x)) anode buffer layer on an indium-tin-oxide (ITO) electrode was used instead of PEDOT:PSS for improving the stability and photovoltaic performance of the polymer solar cells (PSCs). The s-VO(x) layer was prepared by spin-coating a vanadyl

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