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Merck
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文件

195332

Sigma-Aldrich

1-溴十四烷

97%

别名:

十四烷基溴, 肉豆蔻基溴

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About This Item

线性分子式:
CH3(CH2)13Br
CAS号:
112-71-0
分子量:
277.28
Beilstein:
1742640
EC號碼:
203-999-3
MDL號碼:
MFCD00000228
分類程式碼代碼:
12352100
PubChem物質ID:
24851686
NACRES:
NA.22

化驗

97%

形狀

liquid

折射率

n20/D 1.460 (lit.)

bp

175-178 °C/20 mmHg (lit.)

mp

5-6 °C (lit.)

密度

0.932 g/mL at 25 °C (lit.)

SMILES 字串

CCCCCCCCCCCCCCBr

InChI

1S/C14H29Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-14H2,1H3

InChI 密鑰

KOFZTCSTGIWCQG-UHFFFAOYSA-N

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應用

1-溴十四烷可用于合成：
  • 十四烷基二茂铁
  • 阳离子和两性离子双子表面活性剂
  • 基于双[η1(N)-3,4-二烷氧基亚苄基-4′-十二烷基氧基苯胺]二氯钯 (II) 的带有辛基、癸基、十二烷基、十四烷基和十六烷基烷基的金属配位聚合物
  • 9-十四烷基咔唑

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

235.4 °F - closed cup

閃點（°C）

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Atakilt Abebe et al.
Bioinorganic chemistry and applications, 2018, 8097483-8097483 (2018-08-18)
New organic salts were synthesized by quaternizing 1,10-phenanthroline using 1-bromotetradecane. The first step yielded an organic salt of formula [C26H37N2]Br. Anion exchange reaction using Li[(CF3SO2)2N] resulted in a more stable salt of formula [C26H37N2][(CF3SO2)2N]. The organic salts were investigated by
R Hernández-Bravo et al.
The journal of physical chemistry. B, 122(15), 4325-4335 (2018-03-29)
A combined study for understanding the molecular interactions of asphaltenes with molecular species such as ionic liquids (ILs) comprised experimental measurements and computational numerical simulation calculations, using density-functional theory (DFT) with dispersion corrections, molecular dynamics (MD) calculations, and experimental rheological
Novel Metallomesogenic Polymers Derived from ? 1-Benzylideneaniline Palladium (II) Complex.
Lee M, et al.
Macromolecules, 32(8), 2777-2782 (1999)
Katrin Wedeking et al.
Langmuir : the ACS journal of surfaces and colloids, 22(7), 3161-3165 (2006-03-22)
Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was analyzed by
Preparation of a Carbazole-Based Macrocycle Via Precipitation-Driven Alkyne Metathesis.
Zhang W, et al.
Organic Syntheses, 177-191 (2007)
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