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同位素純度
99 atom % D
品質等級
化驗
99% (CP)
形狀
liquid
技術
NMR: suitable
雜質
≤0.5% water
water
折射率
n20/D 1.3835 (lit.)
bp
82 °C (lit.)
密度
0.893 g/mL at 25 °C (lit.)
質量偏移
M+10
SMILES 字串
[2H]OC(C([2H])([2H])[2H])(C([2H])([2H])[2H])C([2H])([2H])[2H]
InChI
1S/C4H10O/c1-4(2,3)5/h5H,1-3H3/i1D3,2D3,3D3,5D
InChI 密鑰
DKGAVHZHDRPRBM-SGLLWXCUSA-N
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一般說明
tert-Butanol-d10 (tert-Butyl alcohol-d10) is a deuterated derivative of tert-butanol. It participates in the synthesis of cyanoacetic acid-tert-butylester-d9. Conformational analysis of 2,3-dihydroxypropanoic acid in tert-butyl alcohol-d10 indicates the dominance of gauche-hydroxyl rotamers (92%) under low pH conditions.
應用
tert-Butanol-d10 may be used in the synthesis of cyanoacetic acid-tert-butylester-d9 and tert-butoxide-d9 (BuOK-d9).
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訊號詞
Danger
危險分類
Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
標靶器官
Central nervous system, Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 1
閃點(°F)
51.8 °F - closed cup
閃點(°C)
11 °C - closed cup
Silacyclobutane as ?Carbanion Pump? in Anionic Polymerization. III. Synthesis of Di-and Tri-block Copolymer by ?Diphenylsilacyclobutane-Potassium tert-Butoxide System
Polymer Journal, 36(10), 856-865 (2004)
Journal of the American Society for Mass Spectrometry, 22(6), 976-988 (2011-09-29)
This work experimentally verifies and proves the two long since postulated matrix-assisted laser desorption/ionization (MALDI) analyte protonation pathways known as the Lucky Survivor and the gas phase protonation model. Experimental differentiation between the predicted mechanisms becomes possible by the use
Magnetic resonance in chemistry : MRC, 44(3), 210-219 (2006-02-16)
Vicinal (1)H--(1)H coupling constants were used to determine the conformational preferences of 2,3-dihydroxypropanoic acid (1) (DL-glyceric acid) in various solvents and its different carboxyl ionization states. The stereospecific assignments of J(12) and J(13) were confirmed through the point-group substitution of
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