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Merck

471712

Sigma-Aldrich

叔丁醇

anhydrous, ≥99.5%

别名:

2-甲基-2-丙醇, 三甲基甲醇, 第三丁醇

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About This Item

线性分子式:
(CH3)3COH
CAS号:
分子量:
74.12
Beilstein:
906698
EC號碼:
MDL號碼:
分類程式碼代碼:
12352001
PubChem物質ID:
NACRES:
NA.21

等級

anhydrous

品質等級

蒸汽密度

2.5 (vs air)

蒸汽壓力

31 mmHg ( 20 °C)
44 mmHg ( 26 °C)

化驗

≥99.5%

形狀

solid or liquid

自燃溫度

896 °F

expl. lim.

8 %

雜質

<0.005% water

蒸發殘留物

<0.0003%

折射率

n20/D 1.387 (lit.)

pH值

7 (20 °C)

bp

83 °C (lit.)

mp

23-26 °C (lit.)

溶解度

water: miscible

密度

0.775 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)(C)O

InChI

1S/C4H10O/c1-4(2,3)5/h5H,1-3H3

InChI 密鑰

DKGAVHZHDRPRBM-UHFFFAOYSA-N

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一般說明

-丁醇(tBA)是一种叔醇。它在固体酸催化剂存在下,发生脱水反应,生成具有高选择性的异丁烯。以大豆油脱臭馏出物(SODD)为反应介质,采用脂肪酶介导的醇解反应制备生物柴油。已有研究关于在锆(TPA/ZrO2)催化剂上负载12-钨磷酸,tBA对甲酚进行丁基化,生成2-丁基甲酚(TBC)、2,6-二丁基对甲酚(DTBC)和丁基甲苯醚。已有采用基于伪势方法的 从头 密度泛函理论(DFT)对tBA在Si(001)-(2×1)表面的相互作用行为进行了评估。

應用


  • Synthesis of Ribose - Oleic Acid Esters in the Presence- and Absence of Candida antarctica Lipase B.: This study investigates the synthesis of ribose-oleic acid esters using tert-Butanol as a solvent, both with and without the presence of Candida antarctica Lipase B. The research explores the efficiency and effectiveness of the enzyme-catalyzed process, highlighting the impact of tert-Butanol on the synthesis reaction. The findings contribute to the understanding of esterification processes in analytical chemistry and have potential applications in developing new synthetic methods (Çetinkaya et al., 2020).

象形圖

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訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

59.0 °F - closed cup

閃點(°C)

15 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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其他客户在看

Lipase-catalyzed biodiesel production from soybean oil deodorizer distillate with absorbent present in tert-butanol system.
Wang L, et al.
Journal of Molecular Catalysis. B, Enzymatic, 43(1), 29-32 (2006)
Atomic and electronic properties of tert-butanol on the Si (001)-(2?1) surface.
Kaderoglu C, et al.
European Physical Journal B: Condensed Matter and Complex Systems, 76(3), 359-363 (2010)
Tert-butanol dehydration to isobutylene via reactive distillation.
Knifton JF, et al.
Catalysis Letters, 73(1), 55-57 (2001)
Alkylation of p-cresol with tert-butanol catalyzed by heteropoly acid supported on zirconia catalyst.
Devassy BM, et al.
J. Mol. Catal. A: Chem., 210(1), 125-130 (2004)
Zaida Lentini et al.
Frontiers in plant science, 11, 522-522 (2020-05-28)
Embryo rescue (ER) in cassava breeding has several relevant applications, from the recovery of broad crosses to the recovery of seeds from the standard pollination program. Cassava fruit setting may drop from 100%, during the 1st week after pollination, to

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