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Merck

149845

Sigma-Aldrich

乙醇铊(I)

别名:

乙醇铊盐, 乙醇铊(I)盐, 铊一氧化硒, 乙氧基亚铊

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About This Item

线性分子式:
TlOC2H5
CAS号:
分子量:
249.44
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

品質等級

反應適用性

core: thallium
reagent type: catalyst

折射率

n20/D 1.676 (lit.)

密度

3.522 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CCO[Tl]

InChI

1S/C2H5O.Tl/c1-2-3;/h2H2,1H3;/q-1;+1

InChI 密鑰

DZFYOYRNBGNPJW-UHFFFAOYSA-N

應用

用HCl还原各种官能团;羰基化合物的立体选择性烯丙基化;原位生成锡烯醇化物用于定向羟醛反应。

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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其他客户在看

S A Frank et al.
Organic letters, 2(17), 2691-2694 (2000-09-16)
[reaction: see text]Thallium(I) ethoxide promotes Suzuki cross couplings for a range of vinyl- and arylboronic acids with vinyl and aryl halide partners in good to excellent yields. This reagent offers distinct advantages over thallium(I) hydroxide in terms of commercial availability
T Tsuchiya et al.
Journal of pharmacobio-dynamics, 12(8), 456-460 (1989-08-01)
The reduction of acute toxicity of paraquat dichloride (PQ) in mice was studied by several sodium sugar sulfates such as dextran sulfate (DS), cellulose sulfate (CS), chondroitin sulfate (CDS), sucrose sulfate (SS) and glucose sulfate (GS). When sugar sulfates (DS
Michel J Kohl et al.
Steroids, 67(1), 71-75 (2001-12-01)
Conjugation of haptens through ether linkages avoids leakage problems in immunoassays, but this procedure is not easily applied to most steroids that bear low reacting hydroxyls. A new technique allowing the ether coupling of biologically active steroids with conjugating arms
Chan, T. H.; Li, C. J.; Wei, Z. Y.,
Journal of the Chemical Society. Chemical Communications, 505-505 (1990)
Yann Sarazin et al.
Journal of the American Chemical Society, 129(4), 881-894 (2007-01-25)
The reaction of thallium ethoxide with [H(OEt2)2][H2N{B(C6F5)3}2] in diethyl ether afforded [Tl(OEt2)3][H2N{B(C6F5)3}2] (2a), [Tl(OEt2)4][H2N{B(C6F5)3}2] (2b), or [Tl(OEt2)2][H2N{B(C6F5)3}2].CH2Cl2 (2c), depending on the reaction conditions. The dication in the hydrolysis product [Tl4(mu3-OH)2][H2N{B(C6F5)3}2]2.4CH2Cl2 consists of two bridging and two terminal Tl+ ions bound

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