144819

1-(三甲基硅氧基)环己烯

99%

• 别名: 1-Cyclohexenyloxytrimethylsilane, 1-环己烯氧基三甲基硅烷
• 线性分子式: C₆H₉OSi(CH₃)₃
• CAS号: 6651-36-1
• 分子量: 170.32
• Beilstein: 1859394
• EC號碼: 229-675-1
• MDL號碼: MFCD00001541
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24848686
• NACRES: NA.22

属性

• 化驗: 99%
• 形狀: liquid
• 折射率: n20/D 1.447 (lit.)
• bp: 64-65 °C/15 mmHg (lit.)
• 密度: 0.875 g/mL at 25 °C (lit.)
• SMILES 字串: C[Si](C)(C)OC1=CCCCC1
• InChI: 1S/C9H18OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
• InChI 密鑰: SBEMOANGDSSPJY-UHFFFAOYSA-N

说明

一般說明

1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).

應用

1-(Trimethylsiloxy)cyclohexene was used in one-pot synthesis of Δ^1,9- octalone. It is intermediate to many complex compounds including natural products.

安全信息

• 象形圖: GHS02
• 訊號詞: Warning
• 危險聲明: H226
• 危險分類: Flam. Liq. 3
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 105.8 °F - closed cup
• 閃點（°C）: 41 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter