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Merck

135194

Sigma-Aldrich

溴代环己烷

98%

别名:

环己基溴

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About This Item

经验公式(希尔记法):
C6H11Br
CAS号:
分子量:
163.06
Beilstein:
1098373
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.495 (lit.)

bp

166-167 °C (lit.)

溶解度

H2O: insoluble
alcohol: soluble

密度

1.324 g/mL at 25 °C (lit.)

官能基

bromo

SMILES 字串

BrC1CCCCC1

InChI

1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2

InChI 密鑰

AQNQQHJNRPDOQV-UHFFFAOYSA-N

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一般說明

溴代环己烷的轴向构象异构体与 9,9′-联蒽基形成包合物,并表现出弱的 1,3-二轴 Cl ... H 相互作用。以石墨作为催化剂,它可参与-二甲苯的烷基化反应,生成烃

應用

通过真空紫外质谱分析阈值电离光谱法,溴代环己烷可用于研究椅基溴环己烷的赤道和轴向构象异构体的电离

象形圖

Environment

危險聲明

防範說明

危險分類

Aquatic Chronic 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

145.4 °F - closed cup

閃點(°C)

63 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Shinya Hirano et al.
Chemical communications (Cambridge, England), (29)(29), 3646-3648 (2005-07-20)
The axial conformers of chloro- and bromocyclohexane were isolated in a pure state as inclusion complexes with 9,9'-bianthryl, and a 1,3 diaxial Cl...H weak interaction was discovered by X-ray analysis of the axial conformer of chlorocyclohexane.
Alkylation on graphite in the absence of Lewis acids.
Sereda GA.
Tetrahedron Letters, 45(39), 7265-7267 (2004)
Songhee Han et al.
The journal of physical chemistry. A, 114(37), 10005-10010 (2010-08-27)
Ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane is investigated with use of the vacuum ultraviolet mass-analyzed threshold ionization (MATI) spectroscopic technique. Two distinct ionization energies of 9.8308 ± 0.0025 and 9.8409 ± 0.0025 eV are determined for
Hanumantha Rao Vutukuri et al.
Angewandte Chemie (International ed. in English), 53(50), 13830-13834 (2014-11-05)
Particle shape is a critical parameter that plays an important role in self-assembly, for example, in designing targeted complex structures with desired properties. Over the last decades, an unprecedented range of monodisperse nanoparticle systems with control over the shape of
Marjolein N van der Linden et al.
Langmuir : the ACS journal of surfaces and colloids, 31(1), 65-75 (2014-12-24)
We studied suspensions of sterically stabilized poly(methyl methacrylate) (PMMA) particles in the solvent cyclohexyl bromide (CHB; εr = 7.92). We performed microelectrophoresis measurements on suspensions containing a single particle species and on binary mixtures, using confocal microscopy to measure the

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