推荐产品
等級
reagent grade
蒸汽壓力
2.6 mmHg ( 25 °C)
化驗
98%
形狀
liquid
折射率
n20/D 1.451 (lit.)
bp
159 °C (lit.)
溶解度
water: insoluble
密度
1.506 g/mL at 25 °C (lit.)
官能基
bromo
ester
SMILES 字串
CCOC(=O)CBr
InChI
1S/C4H7BrO2/c1-2-7-4(6)3-5/h2-3H2,1H3
InChI 密鑰
PQJJJMRNHATNKG-UHFFFAOYSA-N
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一般說明
溴代乙酸乙酯常在有机合成中用作为烷化剂和酰化试剂。溴代乙酸乙酯与对叔丁基杯[4]芳烃进行衍生化反应，生成1,3-二酯取代的杯[4]芳烃。它还与芳基硼酸在氧化铜(I)共催化下发生Suzuki型交叉偶联反应。
應用
溴乙酸乙酯用于在水性介质中制备可逆光敏香豆素稳定的聚合物纳米颗粒，其可用作可检测的药物载体。
訊號詞
Danger
危險分類
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Flam. Liq. 3
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
116.6 °F - closed cup
閃點（°C）
47 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Gillian McMahon et al.
Talanta, 57(6), 1119-1132 (2008-10-31)
A series of derivatisation reactions between p-t-butyl calix[4]arene and ethyl bromoacetate were carried out in order to prepare 1,3 diester substituted calix[4]arene. Mass spectral data, obtained from direct injection of samples, indicated that the reactions were rich in the desired
Jae Woo Chung et al.
Small (Weinheim an der Bergstrasse, Germany), 8(11), 1693-1700 (2012-03-29)
The ability to create aqueous suspended stable nanoparticles of the hydrophobic homopolymer poly(ϵ-caprolactone) end-functionalized with coumarin moieties (CPCL) is demonstrated. Nanoparticles of CPCL are prepared in a continuous manner using nanoprecipitation. The resulting nanoparticles are spherical in morphology, about 40
Occupational allergic contact dermatitis in a chemist from ethyl bromoacetate and bromoacetonitrile.
B Hernández-Machín et al.
Contact dermatitis, 52(2), 115-116 (2005-02-24)
Xing-xin Liu et al.
Chemical communications (Cambridge, England), (6)(6), 622-623 (2002-07-18)
Copper(I) oxide can effectively co-catalyze the Suzuki type cross-coupling reactions of arylboronic acids with ethyl bromoacetate. As an alternative protocol for introducing the methylenecarboxy group into functionalized molecules, this reaction occurs in the absence of highly toxic thallium compounds or
Yaser A-H Mostafa et al.
Archives of pharmacal research, 31(3), 279-293 (2008-04-15)
Certain new derivatives of 1,2,4-triazolo[1,5-a]pyrimidines were synthesized through the reaction of 1,2,4-triazolo[1,5-a]pyrimidine-7-ol with ethyl bromoacetate to afford the ethyl acetate ester, which upon hydrazinolysis gives the corresponding hydrazide. The hydrazide is the key intermediate which was used for the synthesis
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